1Department of Chemistry, University of California Berkeley, Berkeley, CA, USA
2SRI International, Menlo Park, CA 94025, USA
3Department of Earth and Planetary Sciences, University of California Berkeley, Berkeley, CA, USA
*now at: Chemical Sciences Division, Earth Systems Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
**now at: Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
Received: 17 Mar 2011 – Discussion started: 20 Apr 2011
Abstract. We present a new retrieval of tropospheric NO2 vertical column density from the Ozone Monitoring Instrument (OMI) based on high spatial and temporal resolution terrain and profile inputs. We compare our NO2 product, the Berkeley High-Resolution (BEHR) product, with operational retrievals and find that the operational retrievals are biased high (30 %) over remote areas and biased low (8 %) over urban regions. Additionally, we find non-negligible impacts on the retrieved NO2 column for terrain pressure (±20 %), albedo (±40 %), and NO2 vertical profile (−75 %–+10 %). We validate the operational and BEHR products using boundary layer aircraft observations from the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS-CA) field campaign which occurred in June 2008 in California. Results indicate that columns derived using our boundary layer extrapolation method show good agreement with satellite observations (R2 = 0.65–0.83; N = 68) and provide a more robust validation of satellite-observed NO2 column than those determined using full vertical spirals (R2 = 0.26; N = 5) as in previous work. Agreement between aircraft observations and the BEHR product (R2 = 0.83) is better than agreement with the operational products (R2 = 0.65–0.72). We also show that agreement between satellite and aircraft observations can be further improved (e.g. BEHR: R2 = 0.91) using cloud information from the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument instead of the OMI cloud product. These results indicate that much of the variance in the operational products can be attributed to coarse resolution terrain pressure, albedo, and profile parameters implemented in the retrievals.
Revised: 20 Jul 2011 – Accepted: 08 Aug 2011 – Published: 22 Aug 2011
Russell, A. R., Perring, A. E., Valin, L. C., Bucsela, E. J., Browne, E. C., Wooldridge, P. J., and Cohen, R. C.: A high spatial resolution retrieval of NO 2 column densities from OMI: method and evaluation, Atmos. Chem. Phys., 11, 8543-8554, doi:10.5194/acp-11-8543-2011, 2011.