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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Atmos. Chem. Phys., 11, 741-752, 2011
© Author(s) 2011. This work is distributed
under the Creative Commons Attribution 3.0 License.
Research Article
26 Jan 2011
Relating tropical ocean clouds to moist processes using water vapor isotope measurements
J. Lee1, J. Worden1, D. Noone2, K. Bowman1, A. Eldering1, A. LeGrande3, J.-L. F. Li3, G. Schmidt3, and H. Sodemann4
1Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA
2Department of Atmospheric and Oceanic Sciences and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado, USA
3NASA Goddard Institute for Space Studies and Center for Climate Systems Research, Columbia University, New York, New York, USA
4Norwegian Institute for Air Research (NILU), Kjeller, Norway

Abstract. We examine the co-variations of tropospheric water vapor, its isotopic composition and cloud types and relate these distributions to tropospheric mixing and distillation models using satellite observations from the Aura Tropospheric Emission Spectrometer (TES) over the summertime tropical ocean. Interpretation of these process distributions must take into account the sensitivity of the TES isotope and water vapor measurements to variations in cloud, water, and temperature amount. Consequently, comparisons are made between cloud-types based on the International Satellite Cloud Climatology Project (ISSCP) classification; these are clear sky, non-precipitating (e.g., cumulus), boundary layer (e.g., stratocumulus), and precipitating clouds (e.g. regions of deep convection). In general, we find that the free tropospheric vapor over tropical oceans does not strictly follow a Rayleigh model in which air parcels become dry and isotopically depleted through condensation. Instead, mixing processes related to convection as well as subsidence, and re-evaporation of rainfall associated with organized deep convection all play significant roles in controlling the water vapor distribution. The relative role of these moisture processes are examined for different tropical oceanic regions.

Citation: Lee, J., Worden, J., Noone, D., Bowman, K., Eldering, A., LeGrande, A., Li, J.-L. F., Schmidt, G., and Sodemann, H.: Relating tropical ocean clouds to moist processes using water vapor isotope measurements, Atmos. Chem. Phys., 11, 741-752, doi:10.5194/acp-11-741-2011, 2011.
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