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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-11-6985-2011</article-id>
<title-group>
<article-title>Temporal and spatial variability of the stable isotopic composition of atmospheric molecular hydrogen: observations at six EUROHYDROS stations</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Batenburg</surname>
<given-names>A. M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Walter</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pieterse</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Levin</surname>
<given-names>I.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schmidt</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Jordan</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hammer</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Yver</surname>
<given-names>C.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Röckmann</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute for Marine and Atmospheric Research Utrecht, Utrecht University, Utrecht, The Netherlands</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Institut für Umweltphysik, University of Heidelberg, Heidelberg, Germany</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Laboratoire des Sciences du Climat et de l&apos;Environnement, Gif sur Yvette, France</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Max Planck Institut für Biogeochemie, Jena, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>20</day>
<month>07</month>
<year>2011</year>
</pub-date>
<volume>11</volume>
<issue>14</issue>
<fpage>6985</fpage>
<lpage>6999</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/11/6985/2011/acp-11-6985-2011.html">This article is available from http://www.atmos-chem-phys.net/11/6985/2011/acp-11-6985-2011.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/11/6985/2011/acp-11-6985-2011.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/11/6985/2011/acp-11-6985-2011.pdf</self-uri>
<abstract>
<p>Despite the potential of isotope measurements to improve our understanding
of the global atmospheric molecular hydrogen (H&lt;sub&gt;2&lt;/sub&gt;) cycle, few H&lt;sub&gt;2&lt;/sub&gt;
isotope data have been published so far. Now, within the EUROpean network
for atmospheric HYDRogen Observations and Studies project (EUROHYDROS),
weekly to monthly air samples from six locations in a global sampling
network have been analysed for H&lt;sub&gt;2&lt;/sub&gt; mixing ratio (&lt;i&gt;m&lt;/i&gt;(H&lt;sub&gt;2&lt;/sub&gt;)) and the
stable isotopic composition of the H&lt;sub&gt;2&lt;/sub&gt; (&amp;delta;(D,H&lt;sub&gt;2&lt;/sub&gt;), hereafter
referred to as &amp;delta;D). The time series thus obtained now cover one to five years
for all stations. This is the largest set of ground station observations of
&amp;delta;D so far. Annual average &amp;delta;D values are higher at the Southern Hemisphere (SH)
than at the Northern Hemisphere (NH) stations; the maximum is observed at
Neumayer (Antarctica), and the minimum at the non-arctic NH stations. The
maximum seasonal differences in &amp;delta;D range from ≈18 &amp;permil; at Neumayer to
≈45 &amp;permil; at Schauinsland (Southern Germany); in general, seasonal
variability is largest at the NH stations. The timing of minima and maxima
differs per station as well. In Alert (Arctic Canada), the variations in
&amp;delta;D and &lt;i&gt;m&lt;/i&gt;(H&lt;sub&gt;2&lt;/sub&gt;) can be approximated as simple harmonic functions with a
≈5-month relative phase shift. This out-of-phase seasonal
behaviour of &amp;delta;D and &lt;i&gt;m&lt;/i&gt;(H&lt;sub&gt;2&lt;/sub&gt;) can also be detected, but delayed and with a
≈6-month relative phase shift, at Mace Head and Cape Verde.
However, no seasonal &amp;delta;D cycle could be observed at Schauinsland, which likely
reflects the larger influence of local sources and sinks at this continental
station. At the two SH stations, no seasonal cycle could be detected in the
&amp;delta;D data. If it is assumed that the sink processes are the main drivers of the
observed seasonality in &lt;i&gt;m&lt;/i&gt;(H&lt;sub&gt;2&lt;/sub&gt;) and &amp;delta;D on the NH, the relative seasonal
variations can be used to estimate the relative sink strength of the two
major sinks, deposition to soils and atmospheric oxidation by the hydroxyl
(OH) radical. For the NH coastal and marine stations this analysis suggests
that the relative contribution of soil uptake to the total annual H&lt;sub&gt;2&lt;/sub&gt;
removal increases with latitude.</p>
</abstract>
<counts><page-count count="15"/></counts>
</article-meta>
</front>
<body/>
<back>
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