ACP Atmospheric Chemistry and Physics ACP 1680-7324 Copernicus GmbH Göttingen, Germany 10.5194/acp-11-6515-2011 A multi-sensor upper tropospheric ozone product (MUTOP) based on TES Ozone and GOES water vapor: derivation Felker S. R. 1 Moody J. L. 1 Wimmers A. J. 2 Osterman G. 3 Bowman K. 3 University of Virginia, Charlottesville, VA, USA Cooperative Institute for Meteorological Satellite Studies, Madison, WI, USA NASA Jet Propulsion Laboratory, Pasadena, CA, USA 08 07 2011 11 13 6515 6527 This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. This article is available from http://www.atmos-chem-phys.net/11/6515/2011/acp-11-6515-2011.html The full text article is available as a PDF file from http://www.atmos-chem-phys.net/11/6515/2011/acp-11-6515-2011.pdf

The Tropospheric Emission Spectrometer (TES), a hyperspectral infrared instrument on the Aura satellite, retrieves a vertical profile of tropospheric ozone. However, polar-orbiting instruments like TES provide limited nadir-view coverage. This work illustrates the value of these observations when taken in context with geostationary imagery describing synoptic-scale weather patterns. The goal of this study is to create map-view products of upper troposphere (UT) ozone through the integration of TES ozone measurements with two synoptic dynamic tracers of stratospheric influence: specific humidity derived from the GOES Imager water vapor absorption channel, and potential vorticity (PV) from an operational forecast model. As a mixing zone between tropospheric and stratospheric reservoirs, the upper troposphere (UT) exhibits a complex chemical makeup. Determination of ozone mixing ratios in this layer is especially difficult without direct in situ measurement. However, it is well understood that UT ozone is correlated with dynamical tracers like low specific humidity and high potential vorticity. Blending the advantages of two remotely sensed quantities (GOES water vapor and TES ozone) is at the core of the Multi-sensor Upper Tropospheric Ozone Product (MUTOP). <br><br> Our results suggest that 72 % of TES-observed UT ozone variability can be explained by its correlation with dry air and high PV. MUTOP reproduces TES retrievals across the GOES-West domain with a root mean square error (RMSE) of 18 ppbv (part per billion by volume). There are several advantages to this multi-sensor derived product approach: (1) it is calculated from two operational fields (GOES specific humidity and GFS PV), so maps of layer-average ozone can be created and used in near real-time; (2) the product provides the spatial resolution and coverage of a geostationary image as it depicts the variable distribution of ozone in the UT; and (3) the 6 h temporal resolution of the derived product imagery allows for the visualization of rapid movement of this dynamically-driven ozone, as illustrated in the animation Supplement. This paper presents the scientific basis and methodology behind the creation of this unique ozone product, as well as a statistical comparison of the derived product to an evaluation dataset of coincident TES observations.

 References Ancellet, G., Beekmann, M., and Papayannis, A.: Impact of a cutoff low development on downward transport of ozone in the troposphere, J. Geophys. Res.-Atmos., 99, 3451–3468, 1994. Appenzeller, C. and Davies, H. C.: Structure of stratosopheric intrusions into the troposphere, Nature, 358, 570–572, 1992. Appenzeller, C., Holton, J. R., and Rosenlof, K. H.,: Seasonal variation of mass transport across the tropopause, J. Geophys. Res., 101, 15071–15078, 1996. Bader, J. J., Forbes, G. S., Grant, J. R., Lilley, R. B. E., and Waters, A. J. (Eds): Images in Weather Forecasting: A Practical Guide for Interpreting Satellite and Radar Imagery, Cambridge Univ. Press, New York, USA, 1995. Beer, R.: TES on the Aura Mission: Scientific Objectives, Measurements, and Analysis Overview, IEEE T. Geosci. Remote, 44, 1102–1105, 2006. Beer, R., Glavich, T. A., and Rider, D. M.: Tropospheric emission spectrometer for the Earth Observing System's Aura satellite, Appl. Opt., 40(15), 2356–2367, http://dx.doi.org/10.1364/AO.40.002356doi:10.1364/AO.40.002356, 2001. Beuermann, R., Konopka, P., Brunner, D., Bujok, O., Gunther, G., McKenna, D. S., Lelieveld, J., Muller, R., and Schiller, C.: High-resolution measurements and simulation of stratospheric and tropospheric intrusions in the vicinity of the polar jet stream, Geophys. Res. Lett., 29, 1577, http://dx.doi.org/10.1029/2001gl014162doi:10.1029/2001gl014162, 2002. Bowman, K. W., Worden, J., Steck, T., Worden, H. M., Clough, S., and Rodgers, C.: Capturing time and vertical variability of tropospheric ozone: A study using tes nadir retrievals, J. Geophys. Res.-Atmos., 107, 4723, http://dx.doi.org/10.1029/2002jd002150doi:10.1029/2002jd002150, 2002. Bowman, K. W., Rodgers, C. D., Kulawik, S. S., Worden, J., Sarkissian, E., Osterman, G., Steck, T., Lou, M., Eldering, A., Shephard, M., Worden, H., Lampel, M., Clough, S., Brown, P., Rinsland, C., Gunson, M., and Beer, R.: Tropospheric emission spectrometer: Retrieval method and error analysis, IEEE T. Geosci. Remote, 44, 1297–1307, doi:10.1109/TGRS.2006.871234, 2006. Bowman, K. P., Pan, L. L., Campos, T., and Gao, R.: Observations of fine-scale transport structure in the upper troposphere from the high-performance instrumented airborne platform for environmental research, J. Geophys. Res.-Atmos., 112, D18111, http://dx.doi.org/10.1029/2007jd008685doi:10.1029/2007jd008685, 2007. Chandra, S., Ziemke, J. R., and Martin, R. V.: Tropospheric ozone at tropical and middle latitudes derived from TOMS/MLS residual: Comparison with a global model, J. Geophys. Res., 108(D9), 4291, http://dx.doi.org/10.1029/2002JD002912doi:10.1029/2002JD002912, 2003. Cooper, O., Forster, C., Parrish, D., Dunlea, E., Hubler, G., Fehsenfeld, F., Holloway, J., Oltmans, S., Johnson, B., Wimmers, A., and Horowitz, L.: On the life cycle of a stratospheric intrusion and its dispersion into polluted warm conveyor belts, J. Geophys. Res.-Atmos., 109, D23s09, http://dx.doi.org/10.1029/2003jd004006doi:10.1029/2003jd004006, 2004a. Cooper, O. R., Forster, C., Parrish, D., Trainer, M., Dunlea, E., Ryerson, T., Hubler, G., Fehsenfeld, F., Nicks, D., Holloway, J., de Gouw, J., Warneke, C., Roberts, J. M., Flocke, F., and Moody, J.: A case study of transpacific warm conveyor belt transport: Influence of merging airstreams on trace gas import to north america, J. Geophys. Res.-Atmos., 109, D23s08, http://dx.doi.org/10.1029/2003jd003624doi:10.1029/2003jd003624, 2004b. Fairlie, T. D., Avery, M. A., Pierce, R. B., Al-Saadi, J., Dibb, J., and Sachse, G.: Impact of multiscale dynamical processes and mixing on the chemical composition of the upper troposphere and lower stratosphere during the intercontinental chemical transport experiment-north america, J. Geophys. Res.-Atmos., 112, D16s90, http://dx.doi.org/10.1029/2006jd007923doi:10.1029/2006jd007923, 2007. % %Felker, S. R., Moody, J. L., Wimmers, A. J., Osterman, G., and Bowman, K.: A Multi-sensor %Upper Tropospheric Ozone Product (MUTOP) based on TES ozone and GOES water vapor: %derivation, Atmos. Chem. Phys. Discuss., 10, 30055–30087, http://dx.doi.org/10.5194/acpd-10-30055-2010doi:10.5194/acpd-10-30055-2010, 2010 %\blackbox\textbfinserted acpd reference, acp is still submitted. Gauss, M., Myhre, G., Pitari, G., Prather, M. J., Isaksen, I. S. A., Berntsen, T. K., Brasseur, G. P., Dentener, F. J., Derwent, R. G., Hauglustaine, D. A., Horowitz, L. W., Jacob, D. J., Johnson, M., Law, K. S., Mickley, L. J., Muller, J. F., Plantevin, P. H., Pyle, J. A., Rogers, H. L., Stevenson, D. S., Sundet, J. K., van Weele, M., and Wild, O.: Radiative forcing in the 21st century due to ozone changes in the troposphere and the lower stratosphere, J. Geophys. Res.-Atmos., 108, 4292, http://dx.doi.org/10.1029/2002jd002624doi:10.1029/2002jd002624, 2003. Fishman, J. and Larsen, J. C.: Distribution of total ozone and stratospheric ozone in the tropics: Implications for the distribution of tropospheric ozone, J. Geophys. Res., 92(D6), 6627–6634, http://dx.doi.org/10.1029/JD092iD06p06627doi:10.1029/JD092iD06p06627, 1987. Fishman, J., Watson, C. E., Larsen, J. C., and Logan, J. A.: Distributionof tropospheric ozone determined from satellite data, J. Geophys. Res., 95(D4), 3599–3617, 1990. Fishman,~J., Wozniak,~A E., and Creilson,~J K.: Global distribution of tropospheric ozone from satellite measurements using the empirically corrected tropospheric ozone residual technique: Identification of the regional aspects of air pollution, Atmos. Chem. Phys., 3, 893–907, http://dx.doi.org/10.5194/acp-3-893-2003doi:10.5194/acp-3-893-2003, 2003. Gray, L. J., Bithell, M., and Cox, B. D.: The role of specific-humidity fields in the diagnosis of stratosphere troposphere exchange, Geophys. Res. Lett., 21, 2103–2106, 1994. Heinemann, T., Lattanzio, A., and Roveda, F.: The EUMETSAT Multi-sensor Precipitation Estimate~(MPE), http://www.eumetsat.int/groups/ops/documents/document/mpe_introduction_ipwg_2002.pdf, 2002. Hilsenrath, E., Schoeberl, M. R., Douglass, A. R., Bhartia, P. K., Barnett, J., Beer, R., Waters, J., Gunson, M., Froidevaux, L., Gille, J., and Levelt, P. F.: Early data from aura and continuity from uars and toms, Space Sci Rev, 125, 417–430, http://dx.doi.org/10.1007/s11214-006-9074-1doi:10.1007/s11214-006-9074-1, 2006. Hudman, R. C., Jacob, D. J., Cooper, O. R., Evans, M. J., Heald, C. L., Park, R. J., Fehsenfeld, F., Flocke, F., Holloway, J., Hubler, G., Kita, K., Koike, M., Kondo, Y., Neuman, A., Nowak, J., Oltmans, S., Parrish, D., Roberts, J. M., and Ryerson, T.: Ozone production in transpacific asian pollution plumes and implications for ozone air quality in california, J. Geophys. Res.-Atmos., 109, D23s10, http://dx.doi.org/10.1029/2004jd004974doi:10.1029/2004jd004974, 2004. Liniger, M. A. and Davies, H. C.: Substructure of a MAP Streamer, Q .J. R. Meteorol. Soc., 129, 633–651, http://dx.doi.org/10.1256/qj.02.28doi:10.1256/qj.02.28, 2003. Moody, J. L., Felker, S. R., Wimmers, A. J., Osterman, G. Bowman, K., Thompson, A. M., and Tarasick, D. W.: A Multi-sensor Upper Tropospheric Ozone Product (MUTOP) based on TES Ozone and GOES Water Vapor: Validation with Ozonesondes, submitted, Atmos. Chem. Phys., 2011. Nassar, R., Logan, J. A., Worden, H. M., Megretskaia, I. A., Bowman, K. W., Osterman, G. B., Thompson, A. M., Tarasick, D. W., Austin, S., Claude, H., Dubey, M. K., Hocking, W. K., Johnson, B. J., Joseph, E., Merrill, J., Morris, G. A.,Newchurch, M., Oltmans, S. J., Posny, F., Schmidlin, F. J., Vomel, H., Whiteman, D. N., and Whitte, J.C.: Validation of Tropospheric Emission Spectrometer~(TES) nadir ozone profiles using ozonesonde measurements, J. Geophys. Res., 113, D15S17, http://dx.doi.org/10.1029/2007JD008819doi:10.1029/2007JD008819, 2008. Osterman, G. B (Ed.): Tropospheric Emission Spectrometer TES L2 Data User's Guide, version 3.00, Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA, 2007. Pan, L. L., Bowman, K. P., Shapiro, M., Randel, W. J., Gao, R. S., Campos, T., Davis, C., Schauffler, S., Ridley, B. A., Wei, J. C., and Barnet, C.: Chemical behavior of the tropopause observed during the Stratosphere-Troposphere Analyses of the Regional Transport experiment, J. Geophys. Res., 112, D18110, doi:10.1029/2007JD008645, 2007. Richards, N. A. D., Osterman, G. B., Browell, E. V., Hair, J. W., Avery, M., and Li, Q. B.: Validation of tropospheric emission spectrometer ozone profiles with aircraft observations during the intercontinental chemical transport experiment-b, J. Geophys. Res.-Atmos., 113, D16s29, http://dx.doi.org/10.1029/2007jd008815doi:10.1029/2007jd008815, 2008. Rodgers, C. D. and Connor, B. J.: Intercomparison of remote sounding instruments, J. Geophys. Res.-Atmos., 108, 4116, http://dx.doi.org/10.1029/2002jd002299doi:10.1029/2002jd002299, 2003. Shepherd, T. G.: Issues in stratosphere-troposphere coupling, J. Meteorol. Soc. Jpn., 80, 769–792, 2002. Schoeberl, M. R., Ziemke, J. R., Bojkov, B., Livesey, N., Duncan, B., Strahan, S., Froidevaux, L., Kulawik, S., Bhartia, P. K., Chandra, S., Levelt, P. F., Witte, J. C., Thompson, A. M., Cuevas, E., Redondas, A., Tarasick, D. W., Davies, J., Bodeker, G., Hansen, G., Johnson, B. J., Oltmans, S. J., Vomel, H., Allaart, M., Kelder, H., Newchurch, M., Godin-Beekmann, S., Ancellet, G., Claude, H., Andersen, S. B., Kyro, E., Parrondos, M., Yela, M., Zablocki, G., Moore, D., Dier, H., von der Gathen, P., Viatte, P., Stubi, R., Calpini, B., Skrivankova, P., Dorokhov, V., de Backer, H., Schmidlin, F. J., Coetzee, G., Fujiwara, M., Thouret, V., Posny, F., Morris, G., Merrill, J., Leong, C. P., Koenig-Langlo, G., and Joseph, E.: A trajectory-based estimate of the tropospheric ozone column using the residual method, J. Geophys. Res.-Atmos., 112, D24s49, http://dx.doi.org/10.1029/2007JD008773doi:10.1029/2007JD008773, 2007. Singh, H. B., Brune, W. H., Crawford, J. H., Fuelberg, H., and Jacob, D. J.: The Intercontinental Chemical Transport Experiment – Phase B~(INTEX-B): An update, http://www.espo.nasa.gov/docs/intex-b/INTEX-B_WhitePaper.pdf, 2006. Stohl, A., Bonasoni, P., Cristofanelli, P., Collins, W., Feichter, J., Frank, A., Forster, C., Gerasopoulos, E., Gaggeler, H., James, P., Kentarchos, T., Kromp-Kolb, H., Kruger, B., Land, C., Meloen, J., Papayannis, A., Priller, A., Seibert, P., Sprenger, M., Roelofs, G. J., Scheel, H. E., Schnabel, C., Siegmund, P., Tobler, L., Trickl, T., Wernli, H., Wirth, V., Zanis, P., and Zerefos, C.: Stratosphere-troposphere exchange: A review, and what we have learned from staccato, J. Geophys. Res.-Atmos., 108, 8516, http://dx.doi.org/10.1029/2002jd002490doi:10.1029/2002jd002490, 2003. Tarasick, D. W., Moran, M. D., Thompson, A. M., Carey-Smith, T., Rochon, Y., Bouchet, V. S., Gong, W., Makar, P. A., Stroud, C., Menard, S., Crevier, L. P., Cousineau, S., Pudykiewicz, J. A., Kallaur, A., Moffet, R., Menard, R., Robichaud, A., Cooper, O. R., Oltmans, S. J., Witte, J. C., Forbes, G., Johnson, B. J., Merrill, J., Moody, J. L., Morris, G., Newchurch, M. J., Schmidlin, F. J., and Joseph, E.: Comparison of canadian air quality forecast models with tropospheric ozone profile measurements above midlatitude north america during the ions/icartt campaign: Evidence for stratospheric input, J. Geophys. Res.-Atmos., 112, D12s22, http://dx.doi.org/10.1029/2006jd007782doi:10.1029/2006jd007782, 2007. Thompson, A. M., Stone, J. B., Witte, J. C., Miller, S. K., Oltmans, S. J., Kucsera, T. L., Ross, K. L., Pickering, K. E., Merrill, J. T., Forbes, G., Tarasick, D. W., Joseph, E., Schmidlin, F. J., McMillan, W. W., Warner, J., Hintsa, E. J., and Johnson, J. E.: Intercontinental chemical transport experiment ozonesonde network study~(ions) 2004: 2. Tropospheric ozone budgets and variability over northeastern north america, J. Geophys. Res.-Atmos., 112, D12s13, http://dx.doi.org/10.1029/2006jd007670doi:10.1029/2006jd007670, 2007a. Thompson, A. M., Stone, J. B., Witte, J. C., Miller, S. K., Pierce, R. B., Chatfield, R. B., Oltmans, S. J., Cooper, O. R., Loucks, A. L., Taubman, B. F., Johnson, B. J., Joseph, E., Kucsera, T. L., Merrill, J. T., Morris, G. A., Hersey, S., Forbes, G., Newchurch, M. J., Schmidlin, F. J., Tarasick, D. W., Thouret, V., and Cammas, J. P.: Intercontinental chemical transport experiment ozonesonde network study~(ions) 2004: 1. Summertime upper troposphere/lower stratosphere ozone over northeastern north america, J. Geophys. Res.-Atmos., 112, D12s12, http://dx.doi.org/10.1029/2006jd007441doi:10.1029/2006jd007441, 2007b. Thouret, V., Cammas, J.-P., Sauvage, B., Athier, G., Zbinden, R., N$\acute\rm e$d$\acute\rm e$lec, P., Simon, P., and Karcher, F.: Tropopause referenced ozone climatology and inter-annual variability (1994-2003) from the MOZAIC programme, Atmos. Chem. Phys., 6, 1033–1051, http://dx.doi.org/10.5194/acp-6-1033-2006doi:10.5194/acp-6-1033-2006, 2006. Wang, W. C., Liang, X. Z., Dudek, M. P., Pollard, D., and Thompson, S. L.: Atmospheric ozone as a climate gas, Atmos. Res., 37, 247–256, 1995. Wimmers, A. J. and Moody, J. L.: A fixed-layer estimation of upper tropospheric specific humidity from the GOES water vapor channel: Parameterization and validation of the altered brightness temperature product, J. Geophys. Res.-Atmos., 106, 17115–17132, 2001. Wimmers, A. J., Moody, J. L., Browell, E. V., Hair, J. W., Grant, W. B., Butler, C. F., Fenn, M. A., Schmidt, C. C., Li, J., and Ridley, B. A.: Signatures of tropopause folding in satellite imagery, J. Geophys. Res.-Atmos., 108, 8360, http://dx.doi.org/10.1029/2001jd001358doi:10.1029/2001jd001358, 2003. Wimmers, A. J. and Moody, J. L.: Tropopause folding at satellite-observed spatial gradients: 1. Verification of an empirical relationship, J. Geophys. Res.-Atmos., 109, D19306, http://dx.doi.org/10.1029/2003jd004145doi:10.1029/2003jd004145, 2004a. Wimmers, A. J. and Moody, J. L.: Tropopause folding at satellite-observed spatial gradients: 2. Development of an empirical model, J. Geophys. Res.-Atmos., 109, D19307, http://dx.doi.org/10.1029/2003jd004146doi:10.1029/2003jd004146, 2004b. Worden, H. M., Bowman, K. W., Worden, J. R., and Eldering, A.: TES observations of tropospheric ozone as a greenhouse gas,~(Poster) Eos Trans. AGU, 88(52), Fall Meet. Suppl., A51D–0735, 2007a. Worden, H. M., Logan, J. A., Worden, J. R., Beer, R., Bowman, K., Clough, S. A., Eldering, A., Fisher, B. M., Gunson, M. R., Herman, R. L., Kulawik, S. S., Lampel, M. C., Luo, M., Megretskaia, I. A., Osterman, G. B., and Shephard, M. W.: Comparisons of tropospheric emission spectrometer~(tes) ozone profiles to ozonesondes: Methods and initial results, J. Geophys. Res.-Atmos., 112, D03309, http://dx.doi.org/10.1029/2006jd007258doi:10.1029/2006jd007258, 2007b. Worden, J., Kulawik, S. S., Shephard, M. W., Clough, S. A., Worden, H., Bowman, K., and Goldman, A.: Predicted errors of tropospheric emission spectrometer nadir retrievals from spectral window selection, J. Geophys. Res.-Atmos., 109, D09308, http://dx.doi.org/10.1029/2004jd004522doi:10.1029/2004jd004522, 2004. Yang, Q., Cunnold, D.M., Wang, H.-J, Froidevaux, L., Claude, H., Merrill, J., Newchurch, M., and Oltmans, S.J.: Midlatitude tropospheric ozone columns derived from the Aura Ozone Monitoring Instrument and Microwave Limb Sounder measurements, J. Geophys. Res.-Atmos,. 112, D20305, http://dx.doi.org/10.1029/2007JD008528doi:10.1029/2007JD008528, 2007. Ziemke, J. R., Chandra, S., Dunca, B. N., Froidevaux, L., Bhartia, P. K., Levelt, P. F., and Waters, J. W.: Tropospheric ozone determined from Aura OMI and MLS: Evaluation of measurements and comparison with the Global Modeling Initiative's Chemical Transport Model, J. Geophys. Res.-Atmos., 111, D19303, http://dx.doi.org/10.1029/2006JD007089doi:10.1029/2006JD007089, 2006.