1Department of Chemistry and Biochemistry, Kent State University, Kent, OH 44242, USA
2Department of Civil and Environmental Engineering, Washington State University, WA 99164, USA
3National Center for Atmospheric Research, Atmospheric Chemistry Division, Boulder, CO 80307, USA
4Department of Civil Engineering and Center for Environmental Engineering and Science, Indian Institute of Technology, Kanpur 208016, Uttar Pradesh, India
Received: 19 Mar 2011 – Published in Atmos. Chem. Phys. Discuss.: 08 Apr 2011
Abstract. Production of new particles over forests is an important source of cloud condensation nuclei that can affect climate. While such particle formation events have been widely observed, their formation mechanisms over forests are poorly understood. Our observations made in a mixed deciduous forest with large isoprene emissions during the summer displayed a surprisingly rare occurrence of new particle formation (NPF). Typically, NPF events occur around noon but no NPF events were observed during the 5 weeks of measurements. The exceptions were two evening ultrafine particle events. During the day, sulfuric acid concentrations were in the 106 cm−3 range with very low preexisting aerosol particles, a favorable condition for NPF to occur even during the summer. The ratio of emitted isoprene carbon to monoterpene carbon at this site was similar to that in Amazon rainforests (ratio >10), where NPF events are also very rare, compared with a ratio <0.5 in Finland boreal forests, where NPF events are frequent. Our results suggest that large isoprene emissions can suppress NPF formation in forests although the underlying mechanism for the suppression is unclear. The two evening ultrafine particle events were associated with the transported anthropogenic sulfur plumes and ultrafine particles were likely formed via ion-induced nucleation. Changes in landcover and environmental conditions could modify the isoprene suppression of NPF in some forest regions resulting in a radiative forcing that could have influence on the climate.
Revised: 13 Jun 2011 – Accepted: 20 Jun 2011 – Published: 24 Jun 2011
Kanawade, V. P., Jobson, B. T., Guenther, A. B., Erupe, M. E., Pressley, S. N., Tripathi, S. N., and Lee, S.-H.: Isoprene suppression of new particle formation in a mixed deciduous forest, Atmos. Chem. Phys., 11, 6013-6027, doi:10.5194/acp-11-6013-2011, 2011.