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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-11-407-2011</article-id>
<title-group>
<article-title>Insight from ozone and water vapour on transport in the tropical tropopause layer (TTL)</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ploeger</surname>
<given-names>F.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Fueglistaler</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Grooß</surname>
<given-names>J.-U.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Günther</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Konopka</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Liu</surname>
<given-names>Y.S.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Müller</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ravegnani</surname>
<given-names>F.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schiller</surname>
<given-names>C.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ulanovski</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Riese</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute for Chemistry and Dynamics of the Geosphere (ICG-1),  Forschungszentrum Jülich, Jülich, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Applied Mathematics and Theoretical Physics, University of Cambridge,  Cambridge, UK</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>CAO, Dolgoprudny, Russia</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Institute of Atmospheric Sciences and Climate, ISAC-CNR, Bologna, Italy</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Dept. of Geosciences, Princeton University, Princeton, NJ, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>14</day>
<month>01</month>
<year>2011</year>
</pub-date>
<volume>11</volume>
<issue>1</issue>
<fpage>407</fpage>
<lpage>419</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/11/407/2011/acp-11-407-2011.html">This article is available from http://www.atmos-chem-phys.net/11/407/2011/acp-11-407-2011.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/11/407/2011/acp-11-407-2011.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/11/407/2011/acp-11-407-2011.pdf</self-uri>
<abstract>
<p>We explore the potential of ozone observations to constrain transport processes
in the tropical tropopause layer (TTL), and contrast it with insights
that can be obtained from water vapour.
Global fields from Halogen Occultation Experiment (HALOE)
and in-situ observations are predicted
using a backtrajectory approach that captures advection,
instantaneous freeze-drying and photolytical ozone production.
Two different representations of transport (kinematic and diabatic 3-month
backtrajectories based on ERA-Interim data) are used to evaluate the sensitivity to differences in transport.
Results show that mean profiles and seasonality of both tracers can be
reasonably reconstructed. Water vapour predictions are similar
for both transport representations, but predictions for
ozone are systematically higher for kinematic transport.
Compared to global HALOE observations, the diabatic model prediction
underestimates the vertical ozone gradient. Comparison of the kinematic
prediction with observations obtained during the tropical SCOUT-O3 campaign
shows a large high bias above 390 K potential temperature.
We show that ozone predictions and vertical dispersion of the trajectories
are highly correlated, rendering ozone an interesting tracer
for aspects of transport to which water vapour is not sensitive.
We show that dispersion and mean upwelling have similar
effects on ozone profiles, with slower upwelling
and larger dispersion both leading to higher ozone concentrations.
Analyses of tropical upwelling based on mean transport
characteristics, and model validation
have to take into account this ambiguity
between tropical ozone production and in-mixing from the stratosphere.
In turn, ozone provides constraints on transport in the TTL and
lower stratosphere that cannot be obtained from water vapour.</p>
</abstract>
<counts><page-count count="13"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple"> Avallone, L M. and Prather, M J.: Photochemical evolution of ozone in the lower tropical stratosphere, J Geophys. Res., 101, 1457–1461, 1996. </mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple"> Becker, G., Grooß, J.-U., McKenna, D S., and Müller, R.: Stratospheric photolysis frequencies: Impact of an improved numerical solution of the radiative transfer equation, J Atmos. Chem., 37, 217–229, \doi10.1023/A:1006468926530, 2000. </mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple"> Bonazzola, M. and Haynes, P H.: A trajectory-based study of the tropical tropopause region, J Geophys. Res., 109, 20112, \doi10.1029/2003JD004356, 2004. </mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple"> Brewer, A W.: Evidence for a world circulation provided by the measurements of helium and water vapour distribution in the stratosphere, Q J Roy. Meteorol. Soc., 75, 351–363, 1949. </mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple"> Brunner, D., Siegmund, P., May, P T., Chappel, L., Schiller, C., Müller, R., Peter, T., Fueglistaler, S., MacKenzie, A R., Fix, A., Schlager, H., Allen, G., Fjaeraa, A M., Streibel, M., and Harris, N. R P.: The SCOUT-O3 Darwin Aircraft Campaign: rationale and meteorology, Atmos. Chem. Phys., 9, 93–117, doi:10.5194/acp-9-93-2009, 2009. </mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple"> Fueglistaler, S. and Haynes, P H.: Control of interannual and longer-term variability of stratospheric water vapor, J Geophys. Res., 110, 24108, \doi10.1029/2005JD006019, 2005. </mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple"> Fueglistaler, S., Wernli, H., and Peter, T.: Tropical troposphere-to-stratosphere transport inferred from trajectory calculations, J Geophys. Res., 109, D03108, \doi10.1029/2003JD004069, 2004. </mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple"> Fueglistaler, S., Bonazzola, S., Haynes, P H., and Peter, T.: Stratospheric water vapor predicted from the Lagrangian temperature history of air entering the stratosphere in the tropics, J Geophys. Res., 110, 8107, \doi10.1029/2004JD005516, 2005. </mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple"> Fueglistaler, S., Dessler, A E., Dunkerton, T J., Folkins, I., Fu, Q., and Mote, P W.: Tropical Tropopause Layer, Rev. Geophys., 47, RG1004, \doi10.1029/2008RG000267., 2009a. </mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple"> Fueglistaler, S., Legras, B., Beljaars, A., Morcrette, J J., Simmons, A., Tompkins, A M., and Uppala, S.: The diabatic heat budget of the upper troposphere and lower/mid stratosphere in ECMWF reanalysis, Q J Roy. Meteorol. Soc., 135, 21–37, \doi10.1002/qj.361, 2009b. </mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple"> Gettelman, A. and Forster, P M.: Definition and climatology of the tropical tropopause layer, J. Meteorol. Soc. Jpn., 80, 911–924, 2002. </mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple"> Grooß, J.-U. and Russell, J M.: Technical note: A stratospheric climatology for O&lt;sub&gt;3&lt;/sub&gt;, H&lt;sub&gt;2&lt;/sub&gt;O, CH&lt;sub&gt;4&lt;/sub&gt;, NO$_x$, HCl and HF derived from HALOE measurements, Atmos. Chem. Phys., 5, 2797–2807, doi:10.5194/acp-5-2797-2005, 2005. </mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple"> Hall, T M. and Plumb, R A.: Age as a diagnostic of stratospheric transport, J Geophys. Res., 99, 1059–1070, 1994. </mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple"> Highwood, E J. and Hoskins, B J.: The tropical tropopause, Q J Roy. Meteorol. Soc., 124, 1579–1604, 1998. </mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple"> Holton, J R. and Gettelman, A.: Horizontal transport and the dehydration of the stratosphere, Geophys. Res. Lett., 28, 2799–2802, 2001. </mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple"> Holton, J R., Haynes, P., McIntyre, M E., Douglass, A R., Rood, R B., and Pfister, L.: Stratosphere-troposphere exchange, Rev. Geophys., 33, 403–439, 1995. </mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple"> Hoor, P., Wernli, H., Hegglin, M I., and Boenisch, H.: Transport timescales and tracer properties in the extratropical UTLS, Atmos. Chem. Phys., 10, 7929–7944, \doi10.5194/acp-10-7929-2010, 2010. </mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple"> James, R. and Legras, B.: Mixing processes and exchanges in the tropical and the subtropical UT/LS, Atmos. Chem. Phys., 9, 25–38, doi:10.5194/acp-9-25-2009, 2009. </mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple"> James, R., Bonazzola, M., Legras, B., Surbled, K., and Fueglistaler, S.: Water vapor transport and dehydration above convective outflow during Asian monsoon, Geophys. Res. Lett., 35, L20810, \doi10.1029/2008GL035441, 2008. </mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple"> Konopka, P., Günther, G., Müller, R., dos Santos, F. H S., Schiller, C., Ravegnani, F., Ulanovsky, A., Schlager, H., Volk, C M., Viciani, S., Pan, L L., McKenna, D.-S., and Riese, M.: Contribution of mixing to upward transport across the tropical tropopause layer (TTL), Atmos. Chem. Phys., 7, 3285–3308, doi:10.5194/acp-7-3285-2007, 2007. </mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple"> Konopka, P., Grooß, J.-U., Ploeger, F., and Müller, R.: Annual cycle of horizontal in-mixing into the lower tropical stratosphere, J Geophys. Res., 114, D19111, \doi10.1029/2009JD011955, 2009. </mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple"> Konopka, P., Grooß, J U., Günther, G., Ploeger, F., Pommrich, R., Müller, R., and Livesey, N.: Annual cycle of ozone at and above the tropical tropopause: observations versus simulations with the Chemical Lagrangian Model of the Stratosphere (CLaMS), Atmos. Chem. Phys., 10, 121–132, doi:10.5194/acp-10-121-2010, 2010. </mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple"> Krämer, M., Schiller, C., Afchine, A., Bauer, R., Gensch, I., Mangold, A., Schlicht, S., Spelten, N., Sitnikov, N., Borrmann, S., de~Reus, M., and Spichtinger, P.: Ice supersaturations and cirrus cloud crystal numbers, Atmos. Chem. Phys., 9, 3505–3522, doi:10.5194/acp-9-3505-2009, 2009. </mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple"> Kremser, S., Wohltmann, I., Rex, M., Langematz, U., Dameris, M., and Kunze, M.: Water vapour transport in the tropical tropopause region in coupled Chemistry-Climate Models and ERA-40 reanalysis data, Atmos. Chem. Phys., 9, 2679–2694, doi:10.5194/acp-9-2679-2009, 2009. </mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple"> Krüger, K., Tegtmeier, S., and Rex, M.: Long-term climatology of air mass transport through the Tropical Tropopause Layer (TTL) during NH winter, Atmos. Chem. Phys., 8, 813–823, doi:10.5194/acp-8-813-2008, 2008. </mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple"> Legras, B., Joseph, B., and Lefevre, F.: Vertical diffusivity in the lower stratosphere from Lagrangian back-trajectory reconstructions of ozone profiles, J Geophys. Res., 108, 4562, \doi10.1029/2002JD003045, 2003. </mixed-citation>
</ref>
<ref id="ref27">
<label>27</label><mixed-citation publication-type="other" xlink:type="simple"> Liu, S., Fueglistaler, S., and Haynes, P.: Advection-condensation paradigm for stratospheric water vapor, J Geophys. Res., 115, D24307, \doi10.1029/2010JD014352, 2010. </mixed-citation>
</ref>
<ref id="ref28">
<label>28</label><mixed-citation publication-type="other" xlink:type="simple"> McKenna, D S., Grooß, J.-U., Günther, G., Konopka, P., Müller, R., Carver, G., and Sasano, Y.: A new Chemical Lagrangian Model of the Stratosphere (CLaMS): 2. Formulation of chemistry scheme and initialization, J Geophys. Res., 107, 4256, \doi10.1029/2000JD000113, 2002a. </mixed-citation>
</ref>
<ref id="ref29">
<label>29</label><mixed-citation publication-type="other" xlink:type="simple"> McKenna, D S., Konopka, P., Grooß, J.-U., Günther, G., Müller, R., Spang, R., Offermann, D., and Orsolini, Y.: A new Chemical Lagrangian Model of the Stratosphere (CLaMS): 1. Formulation of advection and mixing, J Geophys. Res., 107, 4309, \doi10.1029/2000JD000114, 2002b. </mixed-citation>
</ref>
<ref id="ref30">
<label>30</label><mixed-citation publication-type="other" xlink:type="simple"> Meier, R R., Anderson, D E., J., and Nicolet, M.: Radiation Field in the Troposphere and Stratosphere from 240-1000 nm -I: General Analysis, Planet Space Sci, 30, 923–933, 1982. </mixed-citation>
</ref>
<ref id="ref31">
<label>31</label><mixed-citation publication-type="other" xlink:type="simple"> Monge-Sanz, B M., Chipperfield, M P., Simmons, A J., and Uppala, S M.: Mean age of air and transport in a CTM: Comparison of different ECMWF analyses, Geophys. Res. Lett., 34, L04801, \doi10.1029/2006GL028515, 2007. </mixed-citation>
</ref>
<ref id="ref32">
<label>32</label><mixed-citation publication-type="other" xlink:type="simple"> Mote, P W., Rosenlof, K H., McIntyre, M E., Carr, E S., Gille, J G., Holton, J R., Kinnersley, J S., Pumphrey, H C., Russell III, J M., and Waters, J W.: An atmospheric tape recorder: The imprint of tropical tropopause temperatures on stratospheric water vapor, J Geophys. Res., 101, 3989–4006, 1996. </mixed-citation>
</ref>
<ref id="ref33">
<label>33</label><mixed-citation publication-type="other" xlink:type="simple"> Mote, P W., Dunkerton, T J., McIntyre, M E., Ray, E A., Haynes, P H., and Russell III, J M.: Vertical velocity, vertical diffusion, and dilution by midlatitude air in the tropical lower stratosphere, J Geophys. Res., 103, 8651–8666, 1998. </mixed-citation>
</ref>
<ref id="ref34">
<label>34</label><mixed-citation publication-type="other" xlink:type="simple"> Nash, E R., Newman, P A., Rosenfield, J E., and Schoeberl, M R.: An objective determination of the polar vortex using Ertel&apos;s potential vorticity, J Geophys. Res., 101, 9471–9478, 1996. </mixed-citation>
</ref>
<ref id="ref35">
<label>35</label><mixed-citation publication-type="other" xlink:type="simple"> Osterman, G B., Salawitch, R J., Sen, B., Toon, G C., Stachnik, R A., Pickett, H M., Margitan, J J., and Peterson, D B.: Balloon-borne measurements of stratospheric radicals and their precursors: Implications for the production and loss of ozone, Geophys. Res. Lett., 24, 1107–1110, \doi10.1029/97GL00921, 1997. </mixed-citation>
</ref>
<ref id="ref36">
<label>36</label><mixed-citation publication-type="other" xlink:type="simple"> Pisso, I. and Legras, B.: Turbulent vertical diffusivity in the sub-tropical stratosphere, Atmos. Chem. Phys., 8, 697–707, doi:10.5194/acp-8-697-2008, 2008. </mixed-citation>
</ref>
<ref id="ref37">
<label>37</label><mixed-citation publication-type="other" xlink:type="simple"> Pisso, I., Marecal, V., Legras, B., and Berthet, G.: Sensitivity of ensemble Lagrangian reconstructions to assimilated wind time step resolution, Atmos. Chem. Phys., 10, 3155–3162, doi:10.5194/acp-10-3155-2010, 2010. </mixed-citation>
</ref>
<ref id="ref38">
<label>38</label><mixed-citation publication-type="other" xlink:type="simple"> Ploeger, F., Konopka, P., Günther, G., Grooß, J.-U., and Müller, R.: Impact of the vertical velocity scheme on modeling transport in the tropical tropopause layer, J Geophys. Res., 115, D03301, \doi10.1029/2009JD012023, 2010. </mixed-citation>
</ref>
<ref id="ref39">
<label>39</label><mixed-citation publication-type="other" xlink:type="simple"> Randel, W J., Park, M., Wu, F., and Livesey, N.: A large annual cycle in ozone above the tropical tropopause linked to the Brewer-Dobson circulation, J Atmos. Sci., 64, 4479–4488, 2007. </mixed-citation>
</ref>
<ref id="ref40">
<label>40</label><mixed-citation publication-type="other" xlink:type="simple"> Russell, J M., Gordley, L L., Park, J H., Drayson, S R., Tuck, A F., Harries, J E., Cicerone, R J., Crutzen, P J., and Frederick, J E.: The Halogen Occultation Experiment, J Geophys. Res., 98, 10777–10797, 1993. </mixed-citation>
</ref>
<ref id="ref41">
<label>41</label><mixed-citation publication-type="other" xlink:type="simple"> Schiller, C., Grooß, J.-U., Konopka, P., Ploeger, F., dos Santos, F. H S., and Spelten, N.: Hydration and dehydration at the tropical tropopause, Atmos. Chem. Phys., 9, 9647–9660, doi:10.5194/acp-9-9647-2009, 2009. </mixed-citation>
</ref>
<ref id="ref42">
<label>42</label><mixed-citation publication-type="other" xlink:type="simple"> Schoeberl, M R., Douglass, A R., Zhu, Z X., and Pawson, S.: A comparison of the lower stratospheric age spectra derived from a general circulation model and two data assimilation systems, J Geophys. Res., 108, 4113, \doi10.1029/2002JD002652, 2003. </mixed-citation>
</ref>
<ref id="ref43">
<label>43</label><mixed-citation publication-type="other" xlink:type="simple"> Sherwood, S C.: A stratospheric &quot;drain&quot; over the maritime continent, Geophys. Res. Lett., 27, 677–680, 2000.  </mixed-citation>
</ref>
<ref id="ref44">
<label>44</label><mixed-citation publication-type="other" xlink:type="simple"> Simmons, A., Uppala, S., Dee, S., and Kobayashi, S.: ERA-Interim: New ECMWF reanalysis products from 1989 onwards, ECMWF Newsletter, 110, 25–35, 2006. </mixed-citation>
</ref>
<ref id="ref45">
<label>45</label><mixed-citation publication-type="other" xlink:type="simple"> Sparling, L C., Kettleborough, J A., Haynes, P H., McIntyre, M E., Rosenfield, J E., Schoeberl, M R., and Newman, P A.: Diabatic cross-isentropic dispersion in the lower stratosphere, J Geophys. Res., 102, 25817–25829, 1997. </mixed-citation>
</ref>
<ref id="ref46">
<label>46</label><mixed-citation publication-type="other" xlink:type="simple"> Thompson, A., Witte, J C., Jacquelyn, C., Smit, H. G J., Oltmans, S J., Johnson, B J., Kirchhoff, V. W. J H., and Schmidlin, F J.: Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998–2004 tropical ozone climatology: 3. Instrumentation, station-to-station variability, and evaluation with simulated flight profiles, J Geophys. Res., 112, 3304, \doi10.1029/2005JD007042, 2007. </mixed-citation>
</ref>
<ref id="ref47">
<label>47</label><mixed-citation publication-type="other" xlink:type="simple"> Ulanosvky, A E., Yushkov, V A., Sitnikov, N M., and Ravegnani, F.: The FOZAN-II fast-response chemiluminescent airborne ozone analyzer, Instrum. Exp. Tech., 44, 249–256, 2001. </mixed-citation>
</ref>
<ref id="ref48">
<label>48</label><mixed-citation publication-type="other" xlink:type="simple"> Uppala, S., Dee, S., Kobayashi, S., Berrisford, P., and Simmons, A.: Towards a climate data assimilation system: status update of ERA-Interim, ECMWF Newsletter, 115, 12–18, 2008. </mixed-citation>
</ref>
<ref id="ref49">
<label>49</label><mixed-citation publication-type="other" xlink:type="simple"> Waugh, D W. and Hall, T M.: Age of stratospheric air: Theory, observations, and models, Rev. Geophys., 40, 1–27, 2002. </mixed-citation>
</ref>
<ref id="ref50">
<label>50</label><mixed-citation publication-type="other" xlink:type="simple"> Wennberg, P O., F., H T., Jaegle, L., Jacob, D J., Hintsa, E J., Lanzendorf, E J., Anderson, J G., Gao, R S., Keim, E R., Donnelly, S G., Del~Negro, L A., Fahey, D W., McKeen, S A., Salawitch, R J., Webster, C R., May, R D., Herman, R L., Proffitt, M H., Margitan, J J., Atlas, E L., Schauffler, S M., Flocke, F., McElroy, C T., and Bui, T P.: Hydrogen radicals, nitrogen radicals, and the production of O&lt;sub&gt;3&lt;/sub&gt; in the upper troposphere, Science, 266, 49–53, 1998. </mixed-citation>
</ref>
<ref id="ref51">
<label>51</label><mixed-citation publication-type="other" xlink:type="simple"> Wohltmann, I. and Rex, M.: Improvement of vertical and residual velocities in pressure or hybrid sigma-pressure coordinates in analysis data in the stratosphere, Atmos. Chem. Phys., 8, 265–272, doi:10.5194/acp-8-265-2008, 2008. </mixed-citation>
</ref>
<ref id="ref52">
<label>52</label><mixed-citation publication-type="other" xlink:type="simple"> Zöger, M., Schiller, C., and Eicke, N.: Fast in situ hygrometers: A new family of balloonborne and airborne Lyman-α photofragment fluorescence hygrometers, J Geophys. Res., 104, 1807–1816, 1999. </mixed-citation>
</ref>
</ref-list>
</back>
</article>