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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-11-3581-2011</article-id>
<title-group>
<article-title>Sources of variations in total column carbon dioxide</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Keppel-Aleks</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wennberg</surname>
<given-names>P. O.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schneider</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>California Institute of Technology, Pasadena, California, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>18</day>
<month>04</month>
<year>2011</year>
</pub-date>
<volume>11</volume>
<issue>8</issue>
<fpage>3581</fpage>
<lpage>3593</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<self-uri xlink:href="http://www.atmos-chem-phys.net/11/3581/2011/acp-11-3581-2011.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/11/3581/2011/acp-11-3581-2011.pdf</self-uri>
<abstract>
<p>Observations of gradients in the total CO&lt;sub&gt;2&lt;/sub&gt; column,
&amp;lang;CO&lt;sub&gt;2&lt;/sub&gt;&amp;rang;, are expected to provide improved constraints
on surface fluxes of CO&lt;sub&gt;2&lt;/sub&gt;. Here we use a general circulation model
with a variety of prescribed carbon fluxes to investigate how variations in
&amp;lang;CO&lt;sub&gt;2&lt;/sub&gt;&amp;rang; arise. On diurnal scales, variations are small
and are forced by both local fluxes and advection. On seasonal scales,
gradients are set by the north-south flux distribution. On synoptic scales,
variations arise due to large-scale eddy-driven disturbances of the
meridional gradient. In this case, because variations in
&amp;lang;CO&lt;sub&gt;2&lt;/sub&gt;&amp;rang; are tied to synoptic activity, significant
correlations exist between &amp;lang;CO&lt;sub&gt;2&lt;/sub&gt;&amp;rang; and dynamical
tracers. We illustrate how such correlations can be used to describe the
north-south gradients of &amp;lang;CO&lt;sub&gt;2&lt;/sub&gt;&amp;rang; and the underlying
fluxes on continental scales. These simulations suggest a novel analysis
framework for using column observations in carbon cycle science.</p>
</abstract>
<counts><page-count count="13"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple"> Anderson, J L., Balaji, V., Broccoli, A J., Cooke, W F., Delworth, T L., Dixon, K W., Donner, L J., Dunne, K A., Freidenreich, S M., Garner, S T., Gudgel, R G., Gordon, C T., Held, I M., Hemler, R S., Horowitz, L W., Klein, S A., Knutson, T R., Kushner, P J., Langenhost, A R., Lau, N C., Liang, Z., Malyshev, S L., Milly, P. C D., Nath, M J., Ploshay, J J., Ramaswamy, V., Schwarzkopf, M D., Shevliakova, E., Sirutis, J J., Soden, B J., Stern, W F., Thompson, L A., Wilson, R J., Wittenberg, A T., and Wyman, B L.: The new GFDL global atmosphere and land model AM2-LM2: Evaluation with prescribed SST simulations, J. Climate, 17, 4641–4673, 2004. </mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple"> Andres, R J., Marland, G., Fung, I., and Matthews, E.: A 1 × 1 Distribution of Carbon Dioxide Emissions From Fossil Fuel Consumption and Cement Manufacture, Global Biogeochem. Cy., 10, 419–429, http://dx.doi.org/10.1029/96GB01523doi:10.1029/96GB01523, 1996. </mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple"> Chevallier, F., Breon, F M., and Rayner, P J.: Contribution of the Orbiting Carbon Observatory to the estimation of \chemCO_2 sources and sinks: Theoretical study in a variational data assimilation framework, J. Geophys. Res.-Atmos., 112, D09307, http://dx.doi.org/10.1029/2006JD007375doi:10.1029/2006JD007375, 2007. </mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple"> Chevallier, F., L. Feng, H. Bosch, P I. Palmer, and Rayner,P J.: On the impact of transport model errors for the estimation of surface fluxes from GOSAT observations, Geophys. Res. Lett., 37, L21803, doi:10.1029/2010GL044652, 2010. </mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple"> Ciais, P., Tans, P. P., Trolier, M., White, J. W. C., and Francey, R. J.: A Large Northern-hemisphere Terrestrial $\mathrmCO_2$ Sink Indicated By the C-13/C-12 Ratio of Atmospheric $\mathrmCO_2$, Science, 269, 1098–1102, 1995. </mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple"> Crisp,~D., Atlas,~R M., Breon,~F M., Brown,~L R., Burrows,~J P., Ciais,~P., Connor,~B J., Doney,~S C., Fung,~I Y., Jacob,~D J., Miller,~C E., O&apos;Brien,~D., Pawson,~S., Randerson,~J T., Rayner,~P., Salawitch,~R J., Sander,~S P., Sen,~B., Stephens,~G L., Tans,~P P., Toon,~G C., Wennberg,~P O., Wofsy,~S C., Yung,~Y L., Kuang,~Z M., Chudasama,~B., Sprague,~G., Weiss,~B., Pollock,~R., Kenyon,~D., and Schroll,~S.: The orbiting carbon observatory (OCO) mission, &quot;Trace constituents in the troposphere and lower stratosphere&quot; in the book series, Adv. Space Res., 34, 700–709, 2004. </mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple"> Denning, A S., Fung, I Y., and Randall, D.: Latitudinal Gradient of Atmospheric $\mathrmCO_2$ Due To Seasonal Exchange With Land Biota, Nature, 376, 240–243, 1995. </mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple"> Gurney, K R., Law, R M., Denning, A S., Rayner, P J., Baker, D., Bousquet, P., Bruhwiler, L., Chen, Y.-H., Ciais, P., Fan, S., Fung, I Y., Gloor, M., Heimann, M., Higuchi, K., John, J., Maki, T., Maksyutov, S., Masarie, K., Peylin, P., Prather, M., Pak, B C., Randerson, J., Sarmiento, J., Taguchi, S., Takahashi, T., and Yuen, C.-W.: Towards robust regional estimates of $\mathrmCO_2$ sources and sinks using atmospheric transport models, Nature, 415, 626–630, http://dx.doi.org/10.1038/415626adoi:10.1038/415626a, 2002. </mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple"> Gurney, K R., Law, R M., Denning, A S., Rayner, P J., Pak, B C., Baker, D., Bousquet, P., Bruhwiler, L., Chen, Y H., Ciais, P., Fung, I Y., Heimann, M., John, J., Maki, T., Maksyutov, S., Peylin, P., Prather, M., and Taguchi, S.: Transcom 3 inversion intercomparison: Model mean results for the estimation of seasonal carbon sources and sinks, Global Biogeochem. Cy., 18, GB1010, http://dx.doi.org/10.1029/2003GB002111doi:10.1029/2003GB002111,2004. </mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple"> Hovmöller, E., The trough and ridge diagram: Tellus, 1, 62-66, 1949. </mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple"> Le~Quéré, C., Raupach, M R., Canadell, J G., Marland, G., Bopp, L., Ciais, P., Conway, T J., Doney, S C., Feely, R A., Foster, P., Friedlingstein, P., Gurney, K., Houghton, R A., House, J I., Huntingford, C., Levy, P E., Lomas, M R., Majkut, J., Metzl, N., Ometto, J P., Peters, G P., Prentice, I C., Randerson, J T., Running, S W., Sarmiento, J L., Schuster, U., Sitch, S., Takahashi, T., Viovy, N., van~der Werf, G R., and Woodward, F I.: Trends in the sources and sinks of carbon dioxide, Nature Geosci., 2, 831–836, 2009. </mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple"> Lin, S J.: A &quot;vertically Lagrangian&quot; finite-volume dynamical core for global models, Mon. Weather Rev., 132, 2293–2307, 2004. </mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple"> Marland, G. and Rotty, R M.: Carbon-dioxide Emissions From Fossil-fuels - A Procedure For Estimation and Results For 1950–1982, Tellus B, 36, 232–261, 1984. </mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple"> Miyazaki, K., Patra, P K., Takigawa, M., Iwasaki, T., and Nakazawa, T.: Global-scale transport of carbon dioxide in the troposphere, J. Geophys. Res., 113, D15301, http://dx.doi.org/10.1029/2007JD009557doi:10.1029/2007JD009557, 2008. </mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple"> Miyazaki, K., Machida, T., Patra, P K., Iwasaki, T., Sawa, Y., Matsueda, H., and Nakazawa, T.: Formation mechanisms of latitudinal \chemCO_2 gradients in the upper troposphere over the subtropics and tropics, J. Geophys. Res., 114, D03306, http://dx.doi.org/10.1029/2008JD010545doi:10.1029/2008JD010545, 2009. </mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple"> Nakatsuka, Y. and Maksyutov, S.: Optimization of the seasonal cycles of simulated CO&lt;sub&gt;2&lt;/sub&gt; flux by fitting simulated atmospheric CO&lt;sub&gt;2&lt;/sub&gt; to observed vertical profiles, Biogeosciences, 6, 2733–2741, http://dx.doi.org/10.5194/bg-6-2733-2009doi:10.5194/bg-6-2733-2009, 2009. </mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple"> Nevison, C D., Mahowald, N M., Doney, S C., Lima, I D., Van~der Werf, G R., Randerson, J T., Baker, D F., Kasibhatla, P., and McKinley, G A.: Contribution of ocean, fossil fuel, land biosphere, and biomass burning carbon fluxes to seasonal and interannual variability in atmospheric $\mathrmCO_2$, J. Geophys. Res.-Biogeo., 113, G01010, http://dx.doi.org/10.1029/2007JG000408doi:10.1029/2007JG000408, 2008. </mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple"> Olsen, S C. and Randerson, J T.: Differences between surface and column atmospheric $\mathrmCO_2$ and implications for carbon cycle research, J. Geophys. Res., 109, D02301, http://dx.doi.org/10.1029/2003JD003968doi:10.1029/2003JD003968, 2004. </mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple"> Parrington, M., Jones, D. B. A., Bowman, K. W., Thompson, A. M., Tarasick, D. W., Merrill, J., Oltmans, S. J., Leblanc, T., Witte, J. C, and Millet, D. B.: Impact of the assimilation of ozone from the Tropospheric Emission Spectrometer on surface ozone across North America, Geophys. Res. Lett., 36, L04802, http://dx.doi.org/10.1029/2008GL036935doi:10.1029/2008GL036935, 2009. </mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple"> Peters, W., Jacobson, A R., Sweeney, C., Andrews, A E., Conway, T J., Masarie, K., Miller, J B., Bruhwiler, L. M P., Pétron, G., Hirsch, A I., Worthy, D. E J., van~der Werf, G R., Randerson, J T., Wennberg, P O., Krol, M C., and Tans, P P.: An atmospheric perspective on North American carbon dioxide exchange: CarbonTracker, P. Natl. Acad. Sci., 104, 18925–18930, http://dx.doi.org/10.1073/pnas.0708986104doi:10.1073/pnas.0708986104, 2007. </mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple"> Piao, S L., Ciais, P., Friedlingstein, P., Peylin, P., Reichstein, M., Luyssaert, S., Margolis, H., Fang, J Y., Barr, A., Chen, A P., Grelle, A., Hollinger, D Y., Laurila, T., Lindroth, A., Richardson, A D., and Vesala, T.: Net carbon dioxide losses of northern ecosystems in response to autumn warming, Nature, 451, 49–53, 2008. </mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple"> Randerson, J. T., Thompson, M. V., Conway, T. J., Fung, I. Y., and Field, C. B.: The contribution of terrestrial sources and sinks to trends in the seasonal cycle of atmospheric carbon dioxide, Global Biogeochem. Cy., 11, 535–560, 1997. </mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple"> Sawa, Y., Machida, T., and Matsueda, H.: Seasonal variations of \chemCO_2 near the tropopause observed by commercial aircraft, J. Geophys. Res.-Atmos., 113, D23301, http://dx.doi.org/10.1029/2008JD010568doi:10.1029/2008JD010568, 2008. </mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple"> Stephens, B B., Gurney, K R., Tans, P P., Sweeney, C., Peters, W., Bruhwiler, L., Ciais, P., Ramonet, M., Bousquet, P., Nakazawa, T., Aoki, S., Machida, T., Inoue, G., Vinnichenko, N., Lloyd, J., Jordan, A., Heimann, M., Shibistova, O., Langenfelds, R L., Steele, L P., Francey, R J., and Denning, A S.: Weak northern and strong tropical land carbon uptake from vertical profiles of atmospheric \chemCO_2, Science, 316, 1732–1735, 2007. </mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple"> Takahashi, T., Sutherland, S C., Sweeney, C., Poisson, A., Metzl, N., Tilbrook, B., Bates, N., Wanninkhof, R., Feely, R A., Sabine, C., Olafsson, J., and Nojiri, Y.: Global sea-air \chemCO_2 flux based on climatological surface ocean $p$\chemCO_2, and seasonal biological and temperature effects, Deep-Sea Res. Pt II, 49, 1601–1622, 2002. </mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple"> Washenfelder, R A., Toon, G C., Blavier, J.-F., Yang, Z., Allen, N T., Wennberg, P O., Vay, S A., Matross, D M., and Daube, B C.: Carbon dioxide column abundances at the Wisconsin Tall Tower site, J. Geophys. Res., 111, D22305, http://dx.doi.org/10.1029/2006JD007154doi:10.1029/2006JD007154, 2006. </mixed-citation>
</ref>
<ref id="ref27">
<label>27</label><mixed-citation publication-type="other" xlink:type="simple"> Yang, Z., Washenfelder, R A., Keppel-Aleks, G., Krakauer, N Y., Randerson, J T., Tans, P P., Sweeney, C., and Wennberg, P O.: New constraints on Northern Hemisphere growing season net flux, Geophys. Res. Lett., 34, L12807, http://dx.doi.org/10.1029/2007GL029742doi:10.1029/2007GL029742, 2007. </mixed-citation>
</ref>
<ref id="ref28">
<label>28</label><mixed-citation publication-type="other" xlink:type="simple"> Yokota, T., Yoshida, Y., Eguchi, N., Ota, Y., Tanaka, T., Watanabe, H., and Maksyutov, S.: Global Concentrations of \chemCO_2 and \chemCH_4 Retrieved from GOSAT: First Preliminary Results, Sola, 5, 160–163, 2009. </mixed-citation>
</ref>
</ref-list>
</back>
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