ACP Atmospheric Chemistry and Physics ACP 1680-7324 Copernicus GmbH Göttingen, Germany 10.5194/acp-11-1913-2011 Controls of carbon dioxide concentrations and fluxes above central London Helfter C. 1 Famulari D. 1 Phillips G. J. 1 Barlow J. F. 2 Wood C. R. 2 Grimmond C. S. B. 3 Nemitz E. 1 Centre for Ecology and Hydrology (Edinburgh Research Station), Penicuik, EH26 0QB, UK Department of Meteorology, University of Reading, Reading, RG6 6BB, UK Department of Geography, King's College London, London, UK 02 03 2011 11 5 1913 1928 This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. This article is available from http://www.atmos-chem-phys.net/11/1913/2011/acp-11-1913-2011.html The full text article is available as a PDF file from http://www.atmos-chem-phys.net/11/1913/2011/acp-11-1913-2011.pdf

Eddy-covariance measurements of carbon dioxide fluxes were taken continuously between October 2006 and May 2008 at 190 m height in central London (UK) to quantify emissions and study their controls. Inner London, with a population of 8.2 million (~5000 inhabitants per km<sup>2</sup>) is heavily built up with 8% vegetation cover within the central boroughs. CO<sub>2</sub> emissions were found to be mainly controlled by fossil fuel combustion (e.g. traffic, commercial and domestic heating). The measurement period allowed investigation of both diurnal patterns and seasonal trends. Diurnal averages of CO<sub>2</sub> fluxes were found to be correlated with traffic but also exhibited an inverse dependency on atmospheric stability in the near-neutral range, with higher fluxes coinciding with unstable stratification during most seasons and perhaps reflecting how changes in heating-related natural gas consumption and, to a lesser extent, photosynthetic activity controlled the seasonal variability. Despite measurements being taken at ca. 22 times the mean building height, coupling with street level was adequate, especially during daytime. Night-time saw a higher occurrence of stable or neutral stratification, especially in autumn and winter, which resulted in data loss in post-processing and caused the tower to become decoupled from street level. CO<sub>2</sub> fluxes observed at night were not always correlated with traffic counts, probably reflecting this decoupling, but also the fact that at night heating was always a larger source than traffic. No significant difference was found between the annual estimate of net exchange of CO<sub>2</sub> for the expected measurement footprint and the values derived from the National Atmospheric Emissions Inventory (NAEI), with daytime fluxes differing by only 3%. This agreement with NAEI data also supported the use of the simple flux footprint model which was applied to the London site; this also suggests that individual roughness elements did not significantly affect the measurements due to the large ratio of measurement height to mean building height.

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