<?xml version="1.0" encoding="utf-8" standalone="no"?>
<!DOCTYPE article SYSTEM "http://www.atmos-chem-phys.net/inc/acp/copernicus.dtd">
<article language="en">
	<journal>
		<journal_title>Atmospheric Chemistry and Physics</journal_title>
		<journal_url>www.atmos-chem-phys.net</journal_url>
		<issn>1680-7316</issn>
		<eissn>1680-7324</eissn>
		<volume_number>10</volume_number>
		<issue_number>1</issue_number>
		<publication_year>2010</publication_year>
	</journal>
	<doi>10.5194/acp-10-63-2010</doi>
	<article_url>http://www.atmos-chem-phys.net/10/63/2010/</article_url>
	<abstract_html>http://www.atmos-chem-phys.net/10/63/2010/acp-10-63-2010.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys.net/10/63/2010/acp-10-63-2010.pdf</fulltext_pdf>
	<start_page>63</start_page>
	<end_page>78</end_page>
	<publication_date>2010-01-07</publication_date>
	<article_title content_type="html">Constraint of anthropogenic NO&lt;sub&gt;x&lt;/sub&gt; emissions in China from different sectors: a new methodology using multiple satellite retrievals</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>J.-T. Lin</name>
			<email>jlin5@seas.harvard.edu</email>
		</author>
		<author numeration="2" affiliations="1">
			<name>M. B. McElroy</name>
		</author>
		<author numeration="3" affiliations="2">
			<name>K. F. Boersma</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA</affiliation>
		<affiliation numeration="2" content_type="html">KNMI, Climate Observations Department, De Bilt, The Netherlands</affiliation>
	</affiliations>
	<abstract content_type="html">A new methodology is developed to constrain Chinese anthropogenic emissions
of nitrogen oxides (NO&lt;sub&gt;x&lt;/sub&gt;) from four major sectors (industry, power
plants, mobile and residential) in July 2008. It combines tropospheric
NO&lt;sub&gt;2&lt;/sub&gt; column retrievals from GOME-2 and OMI, taking advantage of their
different passing time over China (~10:00 a.m. LT (local time) versus
~02:00 p.m.) and consistent retrieval algorithms. The approach is based on the
difference of NO&lt;sub&gt;x&lt;/sub&gt; columns at the overpass times of the two instruments;
it thus is less susceptible to the likely systematic errors embedded in
individual retrievals that are consistent with each other. Also, it
explicitly accounts for diurnal variations and uncertainties of NO&lt;sub&gt;x&lt;/sub&gt;
emissions for individual sources. Our best top-down estimate suggests a
national budget of 6.8 TgN/yr (5.5 TgN/yr for East China), close to the a priori
bottom-up emission estimate from the INTEX-B mission for the year of 2006.
The top-down emissions are lower than the a priori near Beijing, in the northeastern
provinces and along the east coast; yet they exceed the a priori over many inland
regions. Systematic errors in satellite retrievals are estimated to lead to
underestimation of top-down emissions by at most 17% (most likely
10%). Effects of other factors on the top-down estimate are typically
less than 15% each, including lightning, soil emissions, mixing in
planetary boundary layer, anthropogenic emissions of carbon monoxide and
volatile organic compounds, magnitude of a priori emissions, assumptions on emission
diurnal variations, and uncertainties in the four sectors. The a posteriori emission
budget is 5.7 TgN/yr for East China.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Acarreta, J. R., De Haan, J. F., and Stammes, P.: Cloud pressure retrieval using the O&lt;sub&gt;2&lt;/sub&gt;-O&lt;sub&gt;2&lt;/sub&gt; absorption band at 477 nm, J. Geophys. Res., 109, D05204, doi:10.1029/2003jd003915, 2004. </reference>
		<reference numeration="2" content_type="text"> Boersma, K. F., Eskes, H. J., and Brinksma, E. J.: Error analysis for tropospheric NO&lt;sub&gt;2&lt;/sub&gt; retrieval from space, J. Geophys. Res., 109, D04311, doi:10.1029/2003jd003962, 2004. </reference>
		<reference numeration="3" content_type="text"> Boersma, K. F., Eskes, H. J., Veefkind, J. P., Brinksma, E. J., van der A, R. J., Sneep, M., van den Oord, G. H. J., Levelt, P. F., Stammes, P., Gleason, J. F., and Bucsela, E. J.: Near-real time retrieval of tropospheric NO&lt;sub&gt;2&lt;/sub&gt; from OMI, Atmos. Chem. Phys., 7, 2103–2118, 2007. </reference>
		<reference numeration="4" content_type="text"> Boersma, K. F., Jacob, D. J., Bucsela, E. J., Perring, A. E., Dirksen, R., van der A, R. J., Yantosca, R. M., Park, R. J., Wenig, M. O., Bertram, T. H., and Cohen, R. C.: Validation of OMI tropospheric NO&lt;sub&gt;2&lt;/sub&gt; observations during INTEX-B and application to constrain NO&lt;sub&gt;x&lt;/sub&gt; emissions over the eastern United States and Mexico, Atmos. Environ., 42, 4480–4497, doi:10.1016/j.atmosenv.2008.02.004, 2008a. </reference>
		<reference numeration="5" content_type="text"> Boersma, K. F., Jacob, D. J., Eskes, H. J., Pinder, R. W., Wang, J., and van der A, R. J.: Intercomparison of SCIAMACHY and OMI tropospheric NO&lt;sub&gt;2&lt;/sub&gt; columns: Observing the diurnal evolution of chemistry and emissions from space, J. Geophys. Res., 113, D16S26, doi:10.1029/2007jd008816, 2008b. </reference>
		<reference numeration="6" content_type="text"> Boersma, K. F., Dirksen, R., Veefkind, J. P., Eskes, H. J., and van der A, R. J.: Dutch OMI~NO&lt;sub&gt;2&lt;/sub&gt; (DOMINO) data product HE5 data file user manual, 2009a. </reference>
		<reference numeration="7" content_type="text"> Boersma, K. F., Jacob, D. J., Trainic, M., Rudich, Y., DeSmedt, I., Dirksen, R., and Eskes, H. J.: Validation of urban NO&lt;sub&gt;2&lt;/sub&gt; concentrations and their diurnal and seasonal variations observed from the SCIAMACHY and OMI sensors using in situ surface measurements in Israeli cities, Atmos. Chem. Phys., 9, 3867–3879, 2009. </reference>
		<reference numeration="8" content_type="text"> Cao, J., Ho, M. S., Lei, Y., Nielsen, C. P., Wang, Y. X., and Zhao, Y.: Reconciling Control of Carbon and Air Pollution with Economic Growth in China: Interim Report on Carbon Tax, Report of the Harvard China Project to the China Sustainable Energy Program of the Energy Foundation, Tsinghua University, Harvard University, Cambridge, MA, US, 2009. </reference>
		<reference numeration="9" content_type="text"> Chen, D., Wang, Y., McElroy, M. B., He, K., Yantosca, R. M., and Le Sager, P.: Regional CO pollution and export in China simulated by the high-resolution nested-grid GEOS-Chem model, Atmos. Chem. Phys., 9, 3825–3839, 2009. </reference>
		<reference numeration="10" content_type="text"> Hains, J., Boersma, F., Kroon, M., Dirksen, R., Volten, H., Swart, D., Richter, A., Wittrock, F., Schoenhardt, A., Wagner, T., Ibrahim, O., Roozendael, M. V., Pinardi, G., Gleason, J., Veefkind, P., and Levelt, P.: Testing and improving OMI DOMINO tropospheric NO&lt;sub&gt;2&lt;/sub&gt; using observations from the DANDELIONS and INTEX-B validation campaigns, J. Geophys. Res., doi:10.1029/2009JD012399, in press, 2009. </reference>
		<reference numeration="11" content_type="text"> Holtslag, A. A. M. and Boville, B. A.: Local versus nonlocal boundary-layer diffusion in a global climate model, J. Climate, 6, 1825–1842, 1993. </reference>
		<reference numeration="12" content_type="text"> Jaégle, L., Steinberger, L., Martin, R. V., and Chance, K.: Global partitioning of NO&lt;sub&gt;x&lt;/sub&gt; sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and soil emissions, Faraday Discuss., 130, 407–423, doi:10.1039/b502128f, 2005. </reference>
		<reference numeration="13" content_type="text"> Lamsal, L., Martin, R., and Donkelaar, A. V.: Seasonal variation in nitrogen oxides at northern midlatitudes as inferred from ground-based and satellite-based observations, GEOS-Chem Meeting, 8~April, 2009a. </reference>
		<reference numeration="14" content_type="text"> Lamsal, L. N., Martin, R. V., van Donkelaar, A., Celarier, E. A., Bucsela, E. J., Boersma, K. F., Dirksen, R., Luo, C., and Wang, Y.: Indirect Validation of Tropospheric Nitrogen Dioxide Retrieved from the OMI Satellite Instrument: Insight into the Seasonal Variation of Nitrogen Oxides at Northern Midlatitudes, J. Geophys. Res., doi:10.1029/2009JD013351, in press, 2009b. </reference>
		<reference numeration="15" content_type="text"> Lin, J. T. and McElroy, M. B.: Impacts of boundary layer mixing on pollutant vertical profiles in the lower troposphere: Implications to satellite remote sensing, Atmos. Environ., submitted, 2009. </reference>
		<reference numeration="16" content_type="text"> Lin, J. T., Wuebbles, D. J., and Liang, X. Z.: Effects of intercontinental transport on surface ozone over the United States: Present and future assessment with a global model, Geophys. Res. Lett., 35, L02805, doi:10.1029/2007gl031415, 2008a. </reference>
		<reference numeration="17" content_type="text"> Lin, J. T., Youn, D., Liang, X. Z., and Wuebbles, D. J.: Global model simulation of summertime US ozone diurnal cycle and its sensitivity to PBL mixing, spatial resolution, and emissions, Atmos. Environ., 42, 8470–8483, doi:10.1016/j.atmosenv.2008.08.012, 2008b. </reference>
		<reference numeration="18" content_type="text"> Martin, R. V., Jacob, D. J., Chance, K., Kurosu, T. P., Palmer, P. I., and Evans, M. J.: Global inventory of nitrogen oxide emissions constrained by space-based observations of NO&lt;sub&gt;2&lt;/sub&gt; columns, J. Geophys. Res., 108, 4537, doi:10.1029/2003jd003453, 2003. </reference>
		<reference numeration="19" content_type="text"> Martin, R. V., Sioris, C. E., Chance, K., Ryerson, T. B., Bertram, T. H., Wooldridge, P. J., Cohen, R. C., Neuman, J. A., Swanson, A., and Flocke, F. M.: Evaluation of space-based constraints on global nitrogen oxide emissions with regional aircraft measurements over and downwind of eastern North America, J. Geophys. Res., 111, D15308, doi:10.1029/2005jd006680, 2006. </reference>
		<reference numeration="20" content_type="text"> McElroy, M. B. and Wang, Y. X. X.: Human and animal wastes: Implications for atmospheric N&lt;sub&gt;2&lt;/sub&gt;O and NO&lt;sub&gt;x&lt;/sub&gt;, Global Biogeochem.l Cy., 19, GB2008, doi10.1029/2004gb002429, 2005. </reference>
		<reference numeration="21" content_type="text"> Mijling, B., Boersma, K. F., Roozendael, M. V., DeSmedt, I., and Kelder, H. M.: Reductions of NO&lt;sub&gt;2&lt;/sub&gt; detected from space during the 2008 Beijing Olympic Games, Geophys. Res. Lett., 36, L13801, doi:10.1029/2009GL038943, 2009. </reference>
		<reference numeration="22" content_type="text"> Pickering, K. E., Wang, Y. S., Tao, W. K., Price, C., and Muller, J. F.: Vertical distributions of lightning NO&lt;sub&gt;x&lt;/sub&gt; for use in regional and global chemical transport models, J. Geophys. Res., 103, 31203–31216, 1998. </reference>
		<reference numeration="23" content_type="text"> Price, C., Penner, J., and Prather, M.: NO&lt;sub&gt;x&lt;/sub&gt; from lightning, 1 Global distribution based on lightning physics, J. Geophys. Res., 102, 5929–5941, 1997. </reference>
		<reference numeration="24" content_type="text"> Richter, A. and Burrows, J. P.: Tropospheric NO&lt;sub&gt;2&lt;/sub&gt; from GOME measurements, Adv. Space Res., 29, 1673–1683, 2002. </reference>
		<reference numeration="25" content_type="text"> Richter, A., Burrows, J. P., Nuss, H., Granier, C., and Niemeier, U.: Increase in tropospheric nitrogen dioxide over China observed from space, Nature, 437, 129–132, doi:10.1038/nature04092, 2005. </reference>
		<reference numeration="26" content_type="text"> Sauvage, B., Martin, R. V., van Donkelaar, A., Liu, X., Chance, K., Jaeglé, L., Palmer, P. I., Wu, S., and Fu, T.-M.: Remote sensed and in situ constraints on processes affecting tropical tropospheric ozone, Atmos. Chem. Phys., 7, 815–838, 2007. </reference>
		<reference numeration="27" content_type="text"> Streets, D. G., Bond, T. C., Carmichael, G. R., Fernandes, S. D., Fu, Q., He, D., Klimont, Z., Nelson, S. M., Tsai, N. Y., Wang, M. Q., Woo, J. H., and Yarber, K. F.: An inventory of gaseous and primary aerosol emissions in Asia in the year 2000, J. Geophys. Res., 108, 8809, doi:10.1029/2002jd003093, 2003. </reference>
		<reference numeration="28" content_type="text"> van der A, R. J., Eskes, H. J., Boersma, K. F., Van Noije, T. P. C., Van Roozendael, M., De Smedt, I., Peters, D., and Meijer, E. W.: Trends, seasonal variability and dominant NO&lt;sub&gt;x&lt;/sub&gt; source derived from a ten year record of NO&lt;sub&gt;2&lt;/sub&gt; measured from space, J. Geophys. Res., 113, D04302, doi:10.1029/2007jd009021, 2008. </reference>
		<reference numeration="29" content_type="text"> Wang, P., Stammes, P., van der A, R., Pinardi, G., and van Roozendael, M.: FRESCO+: an improved O&lt;sub&gt;2&lt;/sub&gt; A-band cloud retrieval algorithm for tropospheric trace gas retrievals, Atmos. Chem. Phys., 8, 6565–6576, 2008. </reference>
		<reference numeration="30" content_type="text"> Wang, X. P., Mauzerall, D. L., Hu, Y. T., Russell, A. G., Larson, E. D., Woo, J. H., Streets, D. G., and Guenther, A.: A high-resolution emission inventory for eastern China in 2000 and three scenarios for 2020, Atmos. Environ., 39, 5917–5933, doi:10.1016/j.atmonsenv.2005.06.051, 2005. </reference>
		<reference numeration="31" content_type="text"> Wang, Y. X., McElroy, M. B., Martin, R. V., Streets, D. G., Zhang, Q., and Fu, T. M.: Seasonal variability of NOx emissions over east China constrained by satellite observations: Implications for combustion and microbial sources, J. Geophys. Res., 112, D06301, doi:10.1029/2006jd007538, 2007. </reference>
		<reference numeration="32" content_type="text"> Wang, Y. X. X., McElroy, M. B., Wang, T., and Palmer, P. I.: Asian emissions of CO and NO&lt;sub&gt;x&lt;/sub&gt;: Constraints from aircraft and Chinese station data, J. Geophys. Res., 109, D24304, doi:10.1029/2004jd005250, 2004. </reference>
		<reference numeration="33" content_type="text"> Wuebbles, D. J., Lei, H., and Lin, J. T.: Intercontinental transport of aerosols and photochemical oxidants from Asia and its consequences, Environ. Pollut., 150, 65–84, doi:10.1016/j.envpol.2007.06.066, 2007. </reference>
		<reference numeration="34" content_type="text"> Yienger, J. J. and Levy, H.: Empirical-model of global soil-biogenis NO$_\rm x$ emissions, J. Geophys. Res., 100, 11447–11464, 1995. </reference>
		<reference numeration="35" content_type="text"> Zhang, L., Jacob, D. J., Boersma, K. F., Jaffe, D. A., Olson, J. R., Bowman, K. W., Worden, J. R., Thompson, A. M., Avery, M. A., Cohen, R. C., Dibb, J. E., Flock, F. M., Fuelberg, H. E., Huey, L. G., McMillan, W. W., Singh, H. B., and Weinheimer, A. J.: Transpacific transport of ozone pollution and the effect of recent Asian emission increases on air quality in North America: an integrated analysis using satellite, aircraft, ozonesonde, and surface observations, Atmos. Chem. Phys., 8, 6117–6136, 2008. </reference>
		<reference numeration="36" content_type="text"> Zhang, Q., Streets, D. G., He, K., Wang, Y., Richter, A., Burrows, J. P., Uno, I., Jang, C. J., Chen, D., Yao, Z., and Lei, Y.: NO&lt;sub&gt;x&lt;/sub&gt; emission trends for China, 1995–2004: The view from the ground and the view from space, J. Geophys. Res., 112, D22306, doi:10.1029/2007jd008684, 2007. </reference>
		<reference numeration="37" content_type="text"> Zhang, Q., Streets, D. G., and He, K.: Satellite observations of recent power plant construction in Inner Mongolia, China, Geophys. Res. Lett., 36, L15809, doi:10.1029/2009GL038984, 2009. </reference>
		<reference numeration="38" content_type="text"> Zhang, Q., Streets, D. G., Carmichael, G. R., He, K. B., Huo, H., Kannari, A., Klimont, Z., Park, I. S., Reddy, S., Fu, J. S., Chen, D., Duan, L., Lei, Y., Wang, L. T., and Yao, Z. L.: Asian emissions in 2006 for the NASA INTEX-B mission, Atmos. Chem. Phys., 9, 5131–5153, 2009. </reference>
		<reference numeration="39" content_type="text"> Zhao, C. and Wang, Y. H.: Assimilated inversion of NO&lt;sub&gt;x&lt;/sub&gt; emissions over east Asia using OMI~NO&lt;sub&gt;2&lt;/sub&gt; column measurements, Geophys. Res. Lett., 36, L06805, doi:10.1029/2008gl037123, 2009. </reference>
		<reference numeration="40" content_type="text"> Zhou, Y., Brunner, D., Boersma, K. F., Dirksen, R., and Wang, P.: An improved tropospheric NO&lt;sub&gt;2&lt;/sub&gt; retrieval for satellite observations in the vicinity of mountainous terrain, Atmos. Meas. Tech. Discuss., 2, 401–416, 2009. </reference>
	</references>
</article>

