Atmos. Chem. Phys., 10, 4879-4892, 2010
www.atmos-chem-phys.net/10/4879/2010/
doi:10.5194/acp-10-4879-2010
© Author(s) 2010. This work is distributed
under the Creative Commons Attribution 3.0 License.
Solid state and sub-cooled liquid vapour pressures of substituted dicarboxylic acids using Knudsen Effusion Mass Spectrometry (KEMS) and Differential Scanning Calorimetry
A. M. Booth1, M. H. Barley1, D. O. Topping1, G. McFiggans1, A. Garforth2, and C. J. Percival1
1School of Earth, Environmental and Atmospheric Science, University of Manchester, UK
2School of Chemical Engineering and Analytical Science, University of Manchester, UK

Abstract. Solid state vapour pressures of a selection of atmospherically important substituted dicarboxylic acids have been measured using Knudsen Effusion Mass Spectrometry (KEMS) over a range of 20 K (298–318 K). Enthalpies of fusion and melting points obtained using Differential Scanning Calorimetry (DSC) were used to obtain sub-cooled liquid vapour pressures. They have been compared to estimation methods used on the E-AIM website. These methods are shown to poorly represent – OH groups in combination with COOH groups. Partitioning calculations have been performed to illustrate the impact of the different estimation methods on organic aerosol mass compared to the use of experimental data.

Citation: Booth, A. M., Barley, M. H., Topping, D. O., McFiggans, G., Garforth, A., and Percival, C. J.: Solid state and sub-cooled liquid vapour pressures of substituted dicarboxylic acids using Knudsen Effusion Mass Spectrometry (KEMS) and Differential Scanning Calorimetry, Atmos. Chem. Phys., 10, 4879-4892, doi:10.5194/acp-10-4879-2010, 2010.
 
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