Atmospheric Chemistry and Physics www.atmos-chem-phys.net 1680-7316 1680-7324 10 3 2010 10.5194/acp-10-1369-2010 http://www.atmos-chem-phys.net/10/1369/2010/ http://www.atmos-chem-phys.net/10/1369/2010/acp-10-1369-2010.html http://www.atmos-chem-phys.net/10/1369/2010/acp-10-1369-2010.pdf 1369 1384 2010-02-05 Ice nucleation and cloud microphysical properties in tropical tropopause layer cirrus E. J. Jensen eric.j.jensen@nasa.gov L. Pfister T.-P. Bui P. Lawson D. Baumgardner NASA Ames Research Center, Moffett Field, CA, USA SPEC Inc., Boulder, CO, USA Centro de Ciencias de la Atmosfera, Universidad Nacional Autonoma de Mexico, Circuito Exterior, Mexico In past modeling studies, it has generally been assumed that the predominant mechanism for nucleation of ice in the uppermost troposphere is homogeneous freezing of aqueous aerosols. However, recent in situ and remote-sensing measurements of the properties of cirrus clouds at very low temperatures in the tropical tropopause layer (TTL) are broadly inconsistent with theoretial predictions based on the homogeneous freezing assumption. The nearly ubiquitous occurence of gravity waves in the TTL makes the predictions from homogeneous nucleation theory particularly difficult to reconcile with measurements. These measured properties include ice number concentrations, which are much lower than theory predicts; ice crystal size distributions, which are much broader than theory predicts; and cloud extinctions, which are much lower than theory predicts. Although other explanations are possible, one way to limit ice concentrations is to have on the order of 50 L^−1 effective ice nuclei (IN) that could nucleate ice at relatively low supersaturations. 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