Atmospheric Chemistry and Physics www.atmos-chem-phys.net 1680-7316 1680-7324 10 3 2010 10.5194/acp-10-1287-2010 http://www.atmos-chem-phys.net/10/1287/2010/ http://www.atmos-chem-phys.net/10/1287/2010/acp-10-1287-2010.html http://www.atmos-chem-phys.net/10/1287/2010/acp-10-1287-2010.pdf 1287 1314 2010-02-05 Contributions from DMS and ship emissions to CCN observed over the summertime North Pacific L. Langley lisa.langley@ec.gc.ca W. R. Leaitch U. Lohmann N. C. Shantz D. R. Worsnop Dalhousie University, Halifax, Nova Scotia, Canada Environment Canada, Toronto, Ontario, Canada Institute for Atmospheric and Climate Science, ETH Zurich, Switzerland University of Toronto, Toronto, Ontario, Canada Aerodyne Research Incorporated, Billerica, Massachusetts, USA now at: Meteorological Service of Canada, Dartmouth, Nova Scotia, Canada now at: Environment Canada, Toronto, Ontario, Canada Measurements of cloud condensation nuclei (CCN) made over the North Pacific Ocean in July 2002 are analysed with concurrent measurements of aerosol number, mass and composition. Overall the CCN are controlled by the sulphate, including one case that suggests particle nucleation and growth resulting from dimethyl sulphide oxidation that enhanced CCN concentrations. Hourly CCN concentrations are correlated with concentrations of sulphate plus methanesulphonic acid (MSA) over the entire study period (<i>r</i>²=0.43 and 0.52 for supersaturations of 0.34% and 0.19%, respectively), and are not well correlated with other organics (<i>r</i>²&lt;0.2). One case study reveals elevated mass and number concentrations of ultrafine and fine organic particles due to regional ship emissions, identified through quadrupole aerosol mass spectrometer (Q-AMS) measurements, during which organic mass concentrations are correlated with CCN values (<i>r</i>²=0.39 and 0.46 for supersaturations of 0.19% and 0.34%, respectively). The evolution of the time series and mass distributions of organics, sulphate and MSA over this timeframe indicate that the regional distribution of small, diffuse ship-sourced organic particles act as condensation sites for sulphur species, resulting in a subsequent increase in number concentrations of CCN. 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