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	<journal>
		<journal_title>Atmospheric Chemistry and Physics</journal_title>
		<journal_url>www.atmos-chem-phys.net</journal_url>
		<issn>1680-7316</issn>
		<eissn>1680-7324</eissn>
		<volume_number>10</volume_number>
		<issue_number>3</issue_number>
		<publication_year>2010</publication_year>
	</journal>
	<doi>10.5194/acp-10-1121-2010</doi>
	<article_url>http://www.atmos-chem-phys.net/10/1121/2010/</article_url>
	<abstract_html>http://www.atmos-chem-phys.net/10/1121/2010/acp-10-1121-2010.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys.net/10/1121/2010/acp-10-1121-2010.pdf</fulltext_pdf>
	<start_page>1121</start_page>
	<end_page>1131</end_page>
	<publication_date>2010-02-03</publication_date>
	<article_title content_type="html">Gaseous elemental mercury depletion events observed at Cape Point during 2007–2008</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>E.-G. Brunke</name>
			<email>ernst.brunke@weathersa.co.za</email>
		</author>
		<author numeration="2" affiliations="1">
			<name>C. Labuschagne</name>
		</author>
		<author numeration="3" affiliations="2">
			<name>R. Ebinghaus</name>
		</author>
		<author numeration="4" affiliations="2">
			<name>H. H. Kock</name>
		</author>
		<author numeration="5" affiliations="3">
			<name>F. Slemr</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">South African Weather Service, P.O. Box 320, Stellenbosch, 7599, South Africa</affiliation>
		<affiliation numeration="2" content_type="html">GKSS Research Centre, Institute for Coastal Research, 21502 Geesthacht, Germany</affiliation>
		<affiliation numeration="3" content_type="html">Max Planck Institute for Chemistry, Atmospheric Chemistry Division, P.O. Box 3060, 55020 Mainz, Germany</affiliation>
	</affiliations>
	<abstract content_type="html">Gaseous mercury in the marine boundary layer has been
measured with a 15 min temporal resolution at the Global Atmosphere Watch
station Cape Point since March 2007. The most prominent features of the data
until July 2008 are the frequent occurrences of pollution (PEs) and
depletion events (DEs). Both types of events originate mostly within a short
transport distance (up to about 100 km), which are embedded in air masses
ranging from marine background to continental. The Hg/CO emission ratios
observed during the PEs are within the range reported for biomass burning
and industrial/urban emissions. The depletion of gaseous mercury during the
DEs is in many cases almost complete and suggests an atmospheric residence
time of elemental mercury as short as a few dozens of hours, which is in
contrast to the commonly used estimate of approximately 1 year. The DEs
observed at Cape Point are not accompanied by simultaneous depletion of
ozone which distinguishes them from the halogen driven atmospheric mercury
depletion events (AMDEs) observed in Polar Regions. Nonetheless, DEs similar
to those observed at Cape Point have also been observed at other places in
the marine boundary layer. Additional measurements of mercury speciation and
of possible mercury oxidants are hence called for to reveal the chemical
mechanism of the newly observed DEs and to assess its importance on larger
scales.</abstract>
	<references>
		<reference numeration="1" content_type="text"> % vor jede Referenz Baker, P. G. L., Brunke, E.-G., Slemr, F., and Crouch, A. M.: Atmospheric mercury measurements at Cape Point, South Africa, Atmos. Environ. 36, 2459–2465, 2002. </reference>
		<reference numeration="2" content_type="text"> Bergan, T. and Rodhe, H., Oxidation of elemental mercury in the atmosphere: constraint imposed by global scale modelling, J. Atmos. Chem., 40, 192–212, 2001. </reference>
		<reference numeration="3" content_type="text"> Banta, R. M., Senff, C. J., White, A. B., Trainer, M., McNider, R. T., Valente, R. J., Mayor, S. D., Alvarez, R. J., Hardesty, R. M., Parrish, D., and Fehsenfeld, F. C.: Daytime buildup and nighttime transport of urban ozone in the boundary layer during a stagnation episode, J. Geophys. Res., 103, 22519–22544, 1998. </reference>
		<reference numeration="4" content_type="text"> Brunke, E.-G. Scheel, H. E., and Seiler, W.: Trends of tropospheric CO, N&lt;sub&gt;2&lt;/sub&gt;O and CH&lt;sub&gt;4&lt;/sub&gt; as observed at Cape Point, South Africa, Atmos. Environ., 24A, 585–595, 1990. </reference>
		<reference numeration="5" content_type="text"> Brunke, E.-G., Labuschagne, C., and Slemr, F.: Gaseous mercury emissions from a fire in the Cape Peninsula, South Africa, during January 2000, Geophys. Res. Lett., 28, 1483–1486, 2001. </reference>
		<reference numeration="6" content_type="text"> Brunke, E.-G., Labuschagne, C., Parker, B., van der Spuy, D., and Whittlestone, S.: Cape Point GAW station $^222$Rn detector: factors affecting sensitivity and accuracy, Atmos. Environ., 36, 2257–2262, 2002. </reference>
		<reference numeration="7" content_type="text"> Brunke, E.-G., Labuschagne, C., Parker, B., Scheel, H. E., and Whittlestone, S.: Baseline air mass selection at Cape Point, South Africa: Application of $^222$Rn and other filter criteria to CO&lt;sub&gt;2&lt;/sub&gt;, Atmos. Environ., 38(33), 5693–5702, 2004. </reference>
		<reference numeration="8" content_type="text"> Calvert, J. G. and Lindberg, S. E.: A modelling study of the mechanism of the halogen-ozone-mercury homogeneous reactions in the troposphere during the polar spring, Atmos. Environ., 37, 4467–4481, 2003. </reference>
		<reference numeration="9" content_type="text"> Cantrell, C. A.: Technical Note: Review of methods for linear least-squares fitting of data and application to atmospheric chemistry problems, Atmos. Chem. Phys., 8, 5477–5487, 2008. </reference>
		<reference numeration="10" content_type="text"> Carpenter, L. J.: Iodine in the marine boundary layer, Chem Rev. 103, 4953–4962, 2003. </reference>
		<reference numeration="11" content_type="text"> Chang, S., McDonald-Buller, E., Kimura, Y., Yarwood, G., Neece, J., Russell, M., Tanaka, P., and Allen, D.: Sensitivity of urban ozone formation to chlorine emission estimates, Atmos. Environ., 36, 4991–5003, 2002. </reference>
		<reference numeration="12" content_type="text"> Cowling, R. M., Holmes, P. M., and Rebelo, A. G.: Plant diversity and endemism, in: The Ecology of Fynbos. Nutrients, Fire and Diversity, edited by: Cowling, R. M., Cape Town: Oxford University Press, 62–112, 1992. </reference>
		<reference numeration="13" content_type="text"> Cowling, R. M., Macdonald, I. A. W., and Simmons, M. T.: The Cape Peninsula, South Africa: physiographical, biological and historical background to an extraordinary hot-spot of biodiversity, Biodivers. Conserv., 5, 527–550, 1996. </reference>
		<reference numeration="14" content_type="text"> Dabrowski, J. M., Ashton, P. J., Murray, K., Leaner, J. J., and Mason, R. P.: Anthropogenic mercury emissions in South Africa: Coal combustion in power plants, Atmos. Environ., 42, 6620–6626, 2008. </reference>
		<reference numeration="15" content_type="text"> Ebinghaus, R., Jennings, S. G., Schroeder, W. H., Berg, T., Donaghy, T., Guentzel, J., Kenny, C., Kock, H. H., Kvietkus, K., Landing, W., Munthe, J., Prestbo, E. M., Schneeberger, D., Slemr, F., Sommar, J., Urba, A., Wallschläger, D., and Xiao, Z.: International field intercomparison measurements of atmospheric mercury species at Mace Head, Ireland, Atmos. Environ., 33, 3063–3073, 1999. </reference>
		<reference numeration="16" content_type="text"> Ebinghaus, R., Kock, H. H., Temme, C., Einax, J. W., Löwe, A. G., Richter, A., Burrows, J. P., and Schroeder, W. H.: Antarctic springtime depletion of atmospheric mercury, Environ. Sci. Technol., 36, 1238–1244, 2002. </reference>
		<reference numeration="17" content_type="text"> EPA: United States Environmental Protection Agency: Mercury Study report to Congress, Vol. II, An Inventory of Anthropogenic Mercury Emissions in the United States, EPA-425/R-97-004, 1997. </reference>
		<reference numeration="18" content_type="text"> GAWSIS: GAW Station information system, online available at: http://gaw.empa.ch/gawsis/reports.asp?StationID=35, last access: February 2010. </reference>
		<reference numeration="19" content_type="text"> Hedgecock, I. M. and Pirrone, N.: Mercury and photochemistry in the marine boundary layer – modelling studies suggest the in situ production of reactive gas phase mercury, Atmos. Environ., 35, 3055–3062, 2001. </reference>
		<reference numeration="20" content_type="text"> Hedgecock, I. M., Trunfio, G. A., Pirrone, N., and Sprovieri, F.: Mercury chemistry in the MBL: Mediterranean case and sensitivity studies using the AMCOTS (Atmospheric Mercury Chemistry over the Sea) model, Atmos. Environ., 39, 7217–7230, 2005. </reference>
		<reference numeration="21" content_type="text"> Holmes, C. D., Jacob, D. J., Mason, R. P., and Jaffe, D. A.: Sources and deposition of reactive gaseous mercury in the marine atmosphere, Atmos. Environ., 43, 2278–2285, 2009. </reference>
		<reference numeration="22" content_type="text"> Kock, H. H., Bieber, E., Ebinghaus, R., Spain, T. G., and Thees, B.: Comparison of long-term trends and seasonal variations of atmospheric mercury concentrations at the two European coastal monitoring stations Mace Head, Ireland, and Zingst, Germany, Atmos. Environ., 39, 7549–7556, 2005. </reference>
		<reference numeration="23" content_type="text"> Lin, C.-J., Pongprueksa, P., Lindberg, S. E., Pehkonen, S. O., Byun, D., and Jang, C.: Scientific uncertainties in atmospheric mercury models I: Model science evaluation, Atmos. Environ., 40, 2911–2928, 2006. </reference>
		<reference numeration="24" content_type="text"> Lindberg, S. E., Brooks, S., Lin, C.-I., Scott, K. I., Landis, M. S., Stevens, R. K., Goodsite, M., and Richter, A.: Dynamic oxidation of gaseous mercury in the Arctic troposphere at polar sunrise, Environ. Sci. Technol., 36, 1245–1256, 2002. </reference>
		<reference numeration="25" content_type="text"> Lindberg, S., Bullock, R., Ebinghaus, R., Engstrom, D., Feng, X., Fitzgerald, W., Pirrone, N., Prestbo, E. M., and Seigneur, C.: A synthesis of progress and uncertainties in attributing the sources of mercury in deposition, Ambio, 36(1), 19–32, 2007. </reference>
		<reference numeration="26" content_type="text"> Lindqvist, O. and Rodhe, H.: Atmospheric mercury – a review, Tellus, 37B, 136–159, 1985. </reference>
		<reference numeration="27" content_type="text"> Mason, R. P. and Sheu, G.-R.: Role of the ocean in the global mercury cycle, Global Biogeochem. Cy., 16(4), 1093–1107, 2002. </reference>
		<reference numeration="28" content_type="text"> Munthe, J., Wangberg, I., Pirrone, N., Iverfeld, A., Ferrara, R., Ebinghaus, R., Feng, R., Gardfeldt, K., Keeler, G. J., Lanzilotta, E., Lindberg, S. E., Lu, J., Mamane, Y., Prestbo, E., Schmolke, S., Schroder, W. H., Sommar, J., Sprovieri, F., Stevens, R. K., Stratton, W., Tuncel, G., and Urba, A.: Intercomparison of methods for sampling and analysis of atmospheric mercury species, Atmos. Environ., 35, 3007–3017, 2001. </reference>
		<reference numeration="29" content_type="text"> Nriagu. J. O.: A global assessment of natural sources of atmospheric trace metals, Nature, 338, 47–49, 1989. </reference>
		<reference numeration="30" content_type="text"> Obrist, D., Gannet Hallar, A., McCubbin, I., Stephens, B. B., and Rahn, T.: Atmospheric mercury concentrations at Storm Peak Laboratory in the Rocky Mountains: Evidence for long-range transport from Asia, boundary layer contributions, and plant mercury uptake, Atmos. Environ. 42, 7579–7589, 2008. </reference>
		<reference numeration="31" content_type="text"> Pacyna, E. G., Pacyna, J. M., and Pirrone, N.: European emissions of atmospheric mercury from anthropogenic sources in 1995, Atmos. Environ., 35, 2987–2996, 2001. </reference>
		<reference numeration="32" content_type="text"> Pirrone, N. and Mason, R. (eds.): Mercury Fate and Transport in the Global Atmosphere: Emissions, Measurements and Models, Springer, Dordrecht, doi:10.1007/978-0-387-93958-2-1, 2009. </reference>
		<reference numeration="33" content_type="text"> Scheel, H. E., Brunke, E.-G., and Seiler, W.: Trace gas measurements at the Monitoring Station Cape Point, South Africa, between 1978 and 1988, J. Atmos. Chem., 11(3), 197–210, 1990. </reference>
		<reference numeration="34" content_type="text"> Schroeder, W. H. and Munthe, J.: Atmospheric mercury – an overview, Atmos. Environ., 32, 809–822, 1998. </reference>
		<reference numeration="35" content_type="text"> Seigneur, C. and Lohman, K.: Effect of bromine chemistry on the atmospheric mercury cycle, J. Geophys. Res., 113, D23309, doi:10.1029/2008JD010262, 2008. </reference>
		<reference numeration="36" content_type="text"> Sillman, S.: The relation between ozone, NOx and hydrocarbons in urban and polluted rural environments, Atmos. Environ., 33, 1821–1845, 1999. </reference>
		<reference numeration="37" content_type="text"> Slemr, F., Schuster, G., and Seiler, W.: Distribution, speciation, and budget of atmospheric mercury, J. Atmos. Chem., 3, 407–434, 1985. </reference>
		<reference numeration="38" content_type="text"> Slemr, F., Brunke, E.-G., Labuschagne, C., and Ebinghaus, R.: Total gaseous mercury concentrations at the Cape Point GAW station and their seasonality, Geophys. Res. Lett., 35, L11807, doi:10.1029/2008GL033741, 2008. </reference>
		<reference numeration="39" content_type="text"> Slemr, F., Ebinghaus, R., Brenninkmeijer, C. A. M., Hermann, M., Kock, H. H., Martinsson, B. G., Schuck, T., Sprung, D., van Velthoven, P., Zahn, A., and Ziereis, H.: Gaseous mercury distribution in the upper troposphere and lower stratosphere observed onboard the CARIBIC passenger aircraft, Atmos. Chem. Phys., 9, 1957–1969, 2009. </reference>
		<reference numeration="40" content_type="text"> Steffen, A., Douglas, T., Amyot, M., Ariya, P., Aspmo, K., Berg, T., Bottenheim, J., Brooks, S., Cobbett, F., Dastoor, A., Dommergue, A., Ebinghaus, R., Ferrari, C., Gardfeldt, K., Goodsite, M. E., Lean, D., Poulain, A. J., Scherz, C., Skov, H., Sommar, J., and Temme, C.: A synthesis of atmospheric mercury depletion event chemistry in the atmosphere and snow, Atmos. Chem. Phys., 8, 1445–1482, 2008. </reference>
		<reference numeration="41" content_type="text"> Swartzendruber, P. C., Jaffe, D. A., Prestbo, E. M., Weiss-Penzias, P., Selin, N. E., Park, R., Jacob, D. J., Strode, S., and Jaeglé, L.: Observations of reactive gaseous mercury in the free troposphere at the Mount Bachelor Observatory, J. Geophys. Res., 111, D24301, doi:10.1029/2006JD007415, 2006. </reference>
		<reference numeration="42" content_type="text"> Tanaka, P. L., Riemer, D. D., Chang, S., Yarwood, G., McDonald-Buller, E. C., Apel, E. C., Orlando, J. J., Silva, P. J., Jimenez, J. L., Canagaratna, M. R., Neece, J. D., Mullins, C. B., and Allen, D. T.: Direct evidence for chlorine-enhanced urban ozone formation in Houston, Texas, Atmos. Environ., 37, 1393–1400, 2003. </reference>
		<reference numeration="43" content_type="text"> Tekran Instruments Corporation: 230 Tech Center Drive, Knoxville, TN 37912 USA, Model 2537 A Mercury Vapour Analyzer, User Manual, online available at: http://www.tekran.com/products/ambient/2537.aspx, last access: February 2010. </reference>
		<reference numeration="44" content_type="text"> Temme, Ch., Einax, J. W., Ebinghaus, R., and Schroeder, W. H.: Measurements of atmospheric mercury species at a coastal site in the Antarctic and over the South Atlantic Ocean during polar summer, Environ. Sci. Technol., 37, 22–31, 2003. </reference>
		<reference numeration="45" content_type="text"> UNEP (United Nations Environment Programme): Global Mercury Assessment, United Nations Environment Programme, Geneva, Switzerland (9–13 September 2002), this document is available from: UNEP Chemicals, 11–13 chemin des Anémones, 1219 Châtelaine, Geneva, Switzerland, 2002. </reference>
		<reference numeration="46" content_type="text"> Weiss-Penzias, P., Jaffe, D. E., McClintick, A., Prestbo, E. M., and Landis, M. S.: Gaseous elemental mercury in the marine boundary layer: evidence for rapid removal in anthropogenic pollution, Environ. Sci. Technol., 37, 3755–3763, 2003. </reference>
		<reference numeration="47" content_type="text"> Weiss-Penzias, P., Jaffe, D., Swartzendruber, P., Hafner, W., Chand, D., and Prestbo, E.: Quantifying Asian and biomass burning sources of mercury using the Hg/CO ratio in pollution plumes observed at the Mount Bachelor Observatory, Atmos. Environ., 41, 4366–4379, 2007. </reference>
		<reference numeration="48" content_type="text"> Whittlestone, S., Robinson, E., and Ryan, S.: Radon at the Mauna Loa Observatory: Transport from distant continents,Atmos. Environ., 26A, 251–260, 1992. </reference>
		<reference numeration="49" content_type="text"> WMO: GAW Report No. 161: 12th WMO/IAEA Meeting of Experts on Carbon Dioxide Concentration and Related Tracers Measurement Techniques (Toronto, Canada, 15-18 September 2003), May 2005, 264~pp., in this report on page 181: Cape Point GAW Station Report, edited by: Brunke, E.-G., Labuschagne, C., and Scheel, E, 181–184, 2005. </reference>
		<reference numeration="50" content_type="text"> York, D.: Least-square fitting of a straight line, Can. J. Phys., 44, 1079–1086, 1966. </reference>
	</references>
</article>

