ACP Atmospheric Chemistry and Physics ACP 1680-7324 Copernicus GmbH Göttingen, Germany 10.5194/acp-10-10255-2010 The sensitivity of secondary organic aerosol component partitioning to the predictions of component properties – Part 1: A systematic evaluation of some available estimation techniques McFiggans G. 1 Topping D. O. 1 Barley M. H. 1 Centre for Atmospheric Sciences, School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK 03 11 2010 10 21 10255 10272 This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. This article is available from http://www.atmos-chem-phys.net/10/10255/2010/acp-10-10255-2010.html The full text article is available as a PDF file from http://www.atmos-chem-phys.net/10/10255/2010/acp-10-10255-2010.pdf

A large number of calculations of the absorptive partitioning of organic compounds have been made using a number of methods to predict the component vapour pressures, <i>p</i><sup>0</sup>, and activity coefficients, <i>γ</i><sub><i>i</i></sub>, required in the calculations. The sensitivities of the predictions in terms of the condensed component masses, volatility, O:C ratio, molar mass and functionality distributions to the choice of <i>p</i><sup>0</sup> and <i>γ</i><sub><i>i</i></sub> models and to the number of components to represent the organic mixture have been systematically compared. The condensed component mass was found to be highly sensitive to the vapour pressure model, and less sensitive to both the activity coefficient model and the number of components used to represent the mixture although the sensitivity to the change in property estimation method increased substantially with increased simplification in the treatment of the organic mixture. This was a general finding and was also clearly evident in terms of the predicted component functionality, O:C ratio, molar mass and volatility distributions of the condensed organic components. Within the limitations of the study, this clearly demonstrates the requirement for more accurate representation of the <i>p</i><sup>0</sup> and <i>γ</i><sub><i>i</i></sub> of the semi-volatile organic proxy components used in simplified models as the degree of simplification increases. This presents an interesting paradox, since such reduction in complexity necessarily leads to divergence from the complex behaviour of real multicomponent atmospheric aerosol.

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